RESONANCE RAMAN SPECTRA OF INTERMEDIATES IN OXIDATION OF PHENOTHIAZINE AND PHENOXAZINE
文献类型：期刊论文
| 作者 | Sun Kai; Xu Guangzhi |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1991 |
| 卷号 | 7期号:1页码:87-91 |
| 关键词 | Phenoxazine Phenothiazine Resonance Raman Spectra |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19910114 |
| 英文摘要 | The resonance Raman spectra of phenothiazine radical cation, phenothiazine dication and phenoxazine dication have been recorded, which have been formed by chemical oxidation of their parent compounda with Br-2 or Pb(Ac)(4). The hands of CNC and CSC skeletal deformations show the most enhancement and large positive shifts from the corresponding parent after one or two electrons are subtracted from phenothiazine. The number of bands in ring C C stretching frequency rouge are increased obviously in the spectrum of phenothiazine dication. The spectral data reveal that the degree of fold along the S-N axis vanishes and a greater aromatic resonance structure cornea into being with the loss of two electrons in phenothiazine. The spectrum of phenoxazine dication is more similar to that of its parent, which shows that the lose of electrons in phenoxazine leads to less structural change compared with phenothiazine. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207573300014 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68519]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun Kai |
| 作者单位 | Acad Sinica, Inst Chem, Natl Lab Struct Chem Unstable & Stable Species, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Kai,Xu Guangzhi. RESONANCE RAMAN SPECTRA OF INTERMEDIATES IN OXIDATION OF PHENOTHIAZINE AND PHENOXAZINE[J]. ACTA PHYSICO-CHIMICA SINICA,1991,7(1):87-91. |
| APA | Sun Kai,&Xu Guangzhi.(1991).RESONANCE RAMAN SPECTRA OF INTERMEDIATES IN OXIDATION OF PHENOTHIAZINE AND PHENOXAZINE.ACTA PHYSICO-CHIMICA SINICA,7(1),87-91. |
| MLA | Sun Kai,et al."RESONANCE RAMAN SPECTRA OF INTERMEDIATES IN OXIDATION OF PHENOTHIAZINE AND PHENOXAZINE".ACTA PHYSICO-CHIMICA SINICA 7.1(1991):87-91. |
入库方式： OAI收割
来源：化学研究所
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