Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive
文献类型:期刊论文
作者 | Li, Wei1; Liu, Han1; Du, Da-Ming1,2 |
刊名 | SYNLETT
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出版日期 | 2009-04-01 |
期号 | 6页码:925-928 |
关键词 | Michael Addition Nitroalkene Catalysis Amino Acids Dbu |
ISSN号 | 0936-5214 |
DOI | 10.1055/s-0028-1088210 |
英文摘要 | A mild Michael addition of glycine imines to aromatic-nitroalkenes catalyzed by 10 mol% DBU with LiOTf as an additive was developed. In most cases, the products could be obtained in good yields (up to 96%) with moderate to good diastereoselectivities (up to 10:1). The selectivity for syn adduct can be reversed to anti when the R group of glycine imines was changed from methyl or ethyl to tert-butyl. |
语种 | 英语 |
WOS记录号 | WOS:000266069100008 |
出版者 | GEORG THIEME VERLAG KG |
源URL | [http://ir.iccas.ac.cn/handle/121111/68521] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Du, Da-Ming |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China 2.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Wei,Liu, Han,Du, Da-Ming. Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive[J]. SYNLETT,2009(6):925-928. |
APA | Li, Wei,Liu, Han,&Du, Da-Ming.(2009).Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive.SYNLETT(6),925-928. |
MLA | Li, Wei,et al."Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive".SYNLETT .6(2009):925-928. |
入库方式: OAI收割
来源:化学研究所
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