Hydrogen Bonding and Crystallization in Biodegradable Multiblock Poly(ester urethane) Copolymer
文献类型：期刊论文
| 作者 | Wang, Wei; Wang, Wenshou; Chen, Xuesi; Ing, Xiabin; Su, Zhaohui1 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2009-04-01 |
| 卷号 | 47期号:7页码:685-695 |
| 关键词 | Crystallization Ftir Hydrogen Bonding Shape-memory Polymer |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.21674 |
| 英文摘要 | The hydrogen bonding and crystallization of a biodegradable poly(ester urethane) copolymer based on poly(L-lactide) (PLLA) as the soft segment were investigated by FTIR. On slow cooling from melt, the onset and the progress of the crystallization of the urethane hard segments were correlated to the position, width, and relative intensity of the hydrogen-bonded N-H stretching band. The interconversion between the "free" and hydrogen-bonded N-H and C=O groups in the urethane units in the process was also revealed by 2D correlation analysis of the FTIR data. The crystallization of the PLLA soft segments was monitored by the ester C=O stretching and the skeletal vibrations. It was revealed that the PLLA crystallization was restricted by the phase separation and the urethane crystallization, and at cooling rates of 10 degrees C/min or higher, the crystallization of the PLLA soft segments was prohibited. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 685-695, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000264561300004 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68527]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Su, Zhaohui |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wei,Wang, Wenshou,Chen, Xuesi,et al. Hydrogen Bonding and Crystallization in Biodegradable Multiblock Poly(ester urethane) Copolymer[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2009,47(7):685-695. |
| APA | Wang, Wei,Wang, Wenshou,Chen, Xuesi,Ing, Xiabin,&Su, Zhaohui.(2009).Hydrogen Bonding and Crystallization in Biodegradable Multiblock Poly(ester urethane) Copolymer.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,47(7),685-695. |
| MLA | Wang, Wei,et al."Hydrogen Bonding and Crystallization in Biodegradable Multiblock Poly(ester urethane) Copolymer".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 47.7(2009):685-695. |
入库方式： OAI收割
来源：化学研究所
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