Preparation of Photodegradable Polypropylene/Clay Composites Based on Nanoscaled TiO2 Immobilized Organoclay
文献类型：期刊论文
| 作者 | Meng, Xiangfu; Wang, Haitao; Qian, Zhongzhong; Gao, Xiaowei; Yi, Qingfeng; Zhang, Shimin; Yang, Mingshu |
| 刊名 | POLYMER COMPOSITES
 |
| 出版日期 | 2009-05-01 |
| 卷号 | 30期号:5页码:543-549 |
| ISSN号 | 0272-8397 |
| DOI | 10.1002/pc.20584 |
| 英文摘要 | Photodegradable polypropylene (PP) composites were prepared via melting blending using PP and titanium dioxide (TiO2) immobilized organically modified montmorillonite (organoclay). TiO2 immobilized organoclay (TiO2-OMT) was synthesized by immobilizing anatase TiO2 nanoparticles on organically modified clay via sol-gel method. The structure and morphology of TiO2-OMT were characterized by XRD and scanning electron microscope (SEM), which showed that anatase TiO2 nanoparticles with the size range of 8-12 nm were uniformly immobilized on the surface of organoclay layers. Diffuse reflection UV-vis spectra revealed TiO2-OMT had similar absorbance characters to that of commercial photocatalyst, Degussa P25. The solid-phase photocatalytic degradation of PP/TiO2-OMT composites was investigated by FTIR, DSC, GPC and SEM. The results indicated that TiO2-OMT enhanced the photodegradation rate of PP under UV irradiation. This was due to that immobilization of TiO2 nanoparticles on organoclay effectively avoided the formation of aggregation, and thereby increased the interface between PP and TiO2 nanoparticles. After 300 h irradiation, the average molecular weight was reduced by two orders of magnitude. This work presented a promising method for preparation of environment-friendly polymer nanocomposites. POLYM. COMPOS., 30:543-549, 2009. (C) 2008 Society of Plastics Engineers |
| 语种 | 英语 |
| WOS记录号 | WOS:000265433500004 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68569]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Mingshu |
| 作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Xiangfu,Wang, Haitao,Qian, Zhongzhong,et al. Preparation of Photodegradable Polypropylene/Clay Composites Based on Nanoscaled TiO2 Immobilized Organoclay[J]. POLYMER COMPOSITES,2009,30(5):543-549. |
| APA | Meng, Xiangfu.,Wang, Haitao.,Qian, Zhongzhong.,Gao, Xiaowei.,Yi, Qingfeng.,...&Yang, Mingshu.(2009).Preparation of Photodegradable Polypropylene/Clay Composites Based on Nanoscaled TiO2 Immobilized Organoclay.POLYMER COMPOSITES,30(5),543-549. |
| MLA | Meng, Xiangfu,et al."Preparation of Photodegradable Polypropylene/Clay Composites Based on Nanoscaled TiO2 Immobilized Organoclay".POLYMER COMPOSITES 30.5(2009):543-549. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。