Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes
文献类型：期刊论文
| 作者 | Wang, Junhua1,2; Zhao, Zhuo1,2; Gong, Feixiang1,2; Li, Shenghai1; Zhang, Suobo1 |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2009-11-24 |
| 卷号 | 42期号:22页码:8711-8717 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/ma901606z |
| 英文摘要 | A new bisphenol monomer, 2,2'-dimethylaminemetllylene-4,4'-biphenol (DABP), was easily prepared by Mannich reaction of dimethylamine and formaldehyde with 4,4'-biphenol. Novel partially fluorinated poly(arylene ether sulfone)s with pendant quaternary ammonium groups were prepared by copolymerization of DABP, 4,4'-biphenol, and 3,3',4,4'- tetrafluorodiphenylsulfone, followed by reaction with iodomethane. The resulting copolymers PSQNI-x (where x represents the molar fraction of DABP in the feed) with high molecular weight exhibited outstanding solubility in polar aprotic solvents; thus, the flexible and tough membranes of PSQNI-x with varying ionic content could be prepared by casting from the DMAc solution. Novel anion exchange membranes, PSQNOH-x, were obtained by an anion exchange of PSQNI-x with 1 N NaOH. All PSQNOH-x membranes showed conductivities above 10(-2) S cm(-1) at room temperature, for example, the hydroxide conductivity of PSQNOH-90 achieved to 8.4 x 10(-2) S cm(-1), which was thus comparable to the proton conductivity of Nafion 117 (i.e., 9.0 x 10(-2) S cm(-1)). |
| 语种 | 英语 |
| WOS记录号 | WOS:000271756500022 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68649]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Suobo |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Junhua,Zhao, Zhuo,Gong, Feixiang,et al. Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes[J]. MACROMOLECULES,2009,42(22):8711-8717. |
| APA | Wang, Junhua,Zhao, Zhuo,Gong, Feixiang,Li, Shenghai,&Zhang, Suobo.(2009).Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes.MACROMOLECULES,42(22),8711-8717. |
| MLA | Wang, Junhua,et al."Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes".MACROMOLECULES 42.22(2009):8711-8717. |
入库方式： OAI收割
来源：化学研究所
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