2-Benzoxazolyl-6-[1-(arylimino)ethyl]pyridyliron(II) Chlorides as Ethylene Oligomerization Catalysts
文献类型：期刊论文
| 作者 | Gao, Rong1,2; Li, Yan1,2; Wang, Fosong1,2; Sun, Wen-Hua1,2 ; Bochmann, Manfred3
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| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2009-09-01 |
| 期号 | 27页码:4149-4156 |
| 关键词 | Iron n Ligands Oligomerization Polymerization |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200900491 |
| 英文摘要 | A series of iron(II) dichloride complexes (Fe1-Fe7) ligated by 2-(2-benzoxazolyl)-6-[1-(arylimino)ethyl]pyridines was synthesized and characterized [aryl = 2,6-R(2)(1)C(6)H(3); R(1) = Me (1), Et (2), iPr (3), Cl (4), Br (5); 2,6-Me(2)C(6)H(2)-4-R(2), R(2) = Me (6), Br (7)]. The molecular structures of Fe1, Fe3, and Fe5 were determined by the single-crystal X-ray diffraction. Complexes Fe1 and Fe3 both display distorted trigonal-bipyramidal geometries, whereas complex Fe5 is a distorted square pyramid. Upon activation with modified methylaluminoxane, all iron complexes showed moderate to good activities [up to ca. 10(6) g(product) X (mol Fe)(-1) h(-1) bar(-1)] for the oligomerization and polymerization of ethylene, with high selectivity for vinyl-terminated oligomers or polyethylene waxes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) |
| 语种 | 英语 |
| WOS记录号 | WOS:000270446000015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68661]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Fosong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Phys, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ E Anglia, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England |
| 推荐引用方式 GB/T 7714 | Gao, Rong,Li, Yan,Wang, Fosong,et al. 2-Benzoxazolyl-6-[1-(arylimino)ethyl]pyridyliron(II) Chlorides as Ethylene Oligomerization Catalysts[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2009(27):4149-4156. |
| APA | Gao, Rong,Li, Yan,Wang, Fosong,Sun, Wen-Hua,&Bochmann, Manfred.(2009).2-Benzoxazolyl-6-[1-(arylimino)ethyl]pyridyliron(II) Chlorides as Ethylene Oligomerization Catalysts.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(27),4149-4156. |
| MLA | Gao, Rong,et al."2-Benzoxazolyl-6-[1-(arylimino)ethyl]pyridyliron(II) Chlorides as Ethylene Oligomerization Catalysts".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .27(2009):4149-4156. |
入库方式： OAI收割
来源：化学研究所
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