The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes
文献类型:期刊论文
作者 | Sun, Zhenyu; Zhao, Yanfei; Xie, Yun; Tao, Ranting; Zhang, Hongye; Huang, Changliang; Liu, Zhimin |
刊名 | GREEN CHEMISTRY
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出版日期 | 2010 |
卷号 | 12期号:6页码:1007-1011 |
ISSN号 | 1463-9262 |
DOI | 10.1039/c002391d |
英文摘要 | In this work, we developed a facile and efficient route to deposit ultra. ne Pt particles onto multi-walled carbon nanotubes (MWNTs) with the aid of tip sonication. The loading of Pt on the MWNTs could attain the very high level of 50 wt% and the size of the Pt particles could be controllably tuned in the range 1.9-3.5 nm with narrow size distributions. The resultant nanocomposites were applied to catalyze the hydrogenation of nitrobenzene under solvent-free conditions. It was demonstrated that the Pt/MWNT catalysts showed excellent activity with a high turnover frequency (e. g., 69 900 h(-1)) as well as superior selectivity to aniline (e. g., >99%) in this reaction. |
语种 | 英语 |
WOS记录号 | WOS:000278534900013 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.iccas.ac.cn/handle/121111/68701] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Zhimin |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Zhenyu,Zhao, Yanfei,Xie, Yun,et al. The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes[J]. GREEN CHEMISTRY,2010,12(6):1007-1011. |
APA | Sun, Zhenyu.,Zhao, Yanfei.,Xie, Yun.,Tao, Ranting.,Zhang, Hongye.,...&Liu, Zhimin.(2010).The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes.GREEN CHEMISTRY,12(6),1007-1011. |
MLA | Sun, Zhenyu,et al."The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes".GREEN CHEMISTRY 12.6(2010):1007-1011. |
入库方式: OAI收割
来源:化学研究所
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