Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species
文献类型：期刊论文
| 作者 | Li, Dongzhen1,2; Guang, Jie1,2; Zhang, Wen-Xiong1,2,3; Wang, Yang1,2; Xi, Zhenfeng1,2 |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 8期号:8页码:1816-1820 |
| ISSN号 | 1477-0520 |
| DOI | 10.1039/b923249b |
| 英文摘要 | Zn(OTf)(2) acts as an excellent catalyst precursor for addition of various amine N-H bonds to carbodiimides under an atmosphere of air, offering a convenient synthesis of substituted guanidines with high functional-group tolerance. A Zn-N amido species is shown to act as the active species. |
| 语种 | 英语 |
| WOS记录号 | WOS:000276192100011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68765]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | 1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Dongzhen,Guang, Jie,Zhang, Wen-Xiong,et al. Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2010,8(8):1816-1820. |
| APA | Li, Dongzhen,Guang, Jie,Zhang, Wen-Xiong,Wang, Yang,&Xi, Zhenfeng.(2010).Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species.ORGANIC & BIOMOLECULAR CHEMISTRY,8(8),1816-1820. |
| MLA | Li, Dongzhen,et al."Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species".ORGANIC & BIOMOLECULAR CHEMISTRY 8.8(2010):1816-1820. |
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来源：化学研究所
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