Enhancing the Toughness of Regenerated Silk Fibroin Film through Uniaxial Extension
文献类型:期刊论文
作者 | Yin, Jianwei1; Chen, Erqiang2; Porter, David3; Shao, Zhengzhong1 |
刊名 | BIOMACROMOLECULES
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出版日期 | 2010-11-01 |
卷号 | 11期号:11页码:2890-2895 |
ISSN号 | 1525-7797 |
DOI | 10.1021/bm100643q |
英文摘要 | Films of regenerated silk fibroin (1617) are usually brittle and weak, which prevents its wide application as a structural material. To improve the mechanical properties of RSF film, uniaxial extension under swollen conditions was employed to introduce preferred orientation of molecular chains of silk fibroin. Such a prestretching treatment resulted in the strain at break, ultimate stress, Young's modulus, and energy to break along the predrawn direction of the RSF film increasing from approximate 5%, 90 MPa, 2.7 GPa, and 2.1 kJ/kg to 35%, 169 MPa, 3.5 GPa, and 38.9 kJ/kg, respectively, which is an attractive combination of strength and toughness. The mechanism of these property enhancements was investigated using techniques such as small-angle X-ray scattering, wide-angle X-ray diffraction, atomic force microscopy, and dynamic mechanical analysis. |
语种 | 英语 |
WOS记录号 | WOS:000283810900009 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/68823] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Shao, Zhengzhong |
作者单位 | 1.Fudan Univ, Dept Macromol Sci, Adv Mat Lab, Key Lab Mol Engn Polymers,Minist Educ, Shanghai 200433, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China 3.Univ Oxford, Dept Zool, Oxford OX1 3PS, England |
推荐引用方式 GB/T 7714 | Yin, Jianwei,Chen, Erqiang,Porter, David,et al. Enhancing the Toughness of Regenerated Silk Fibroin Film through Uniaxial Extension[J]. BIOMACROMOLECULES,2010,11(11):2890-2895. |
APA | Yin, Jianwei,Chen, Erqiang,Porter, David,&Shao, Zhengzhong.(2010).Enhancing the Toughness of Regenerated Silk Fibroin Film through Uniaxial Extension.BIOMACROMOLECULES,11(11),2890-2895. |
MLA | Yin, Jianwei,et al."Enhancing the Toughness of Regenerated Silk Fibroin Film through Uniaxial Extension".BIOMACROMOLECULES 11.11(2010):2890-2895. |
入库方式: OAI收割
来源:化学研究所
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