Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate
文献类型：期刊论文
| 作者 | Wang, Zhuo1; Bai, Feng-Ying1; Xing, Yong-Heng1; Xie, Yan1; Ge, Mao-Fa2; Niu, Shu-Yun1 |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 363期号:4页码:669-675 |
| 关键词 | Lanthanide Complexes Luminescent Properties Sebacate Acid Synthesis 2 5-pyridinedicarboxylic Acid |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2009.11.021 |
| 英文摘要 | By using 2,5-pyridinedicarboxylate and sebacate as rigid and flexible mixed carboxylate linkers, five new 3D lanthanide complexes, [Ln(seb)(0.5)(2,5-pydc)(H2O)] (Ln = Eu (1), Nd (2), Sm (3), Pr (4) and Tb (5), H(2)pydc = 2,5-pyridinedicarboxylic acid, H(2)seb = sebacate acid) with macroporous structures, have been synthesized. Complexes 1-5 were characterized by elemental analysis, ICP spectrometer and IR spectroscopy. In particular, the structures of 1-3 were further determined by single-crystal X-ray diffraction. Structural analyses reveal that complexes 1-3 have intricate 3D frameworks, which are constructed by 2,5-pyridinedicarboxylate and sebacate ligands. In addition, the thermogravimetric analysis of 1-3 and photoluminescent properties of 1 and 5 are also discussed in detail. (C) 2009 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000274414700005 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68855]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yong-Heng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zhuo,Bai, Feng-Ying,Xing, Yong-Heng,et al. Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate[J]. INORGANICA CHIMICA ACTA,2010,363(4):669-675. |
| APA | Wang, Zhuo,Bai, Feng-Ying,Xing, Yong-Heng,Xie, Yan,Ge, Mao-Fa,&Niu, Shu-Yun.(2010).Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate.INORGANICA CHIMICA ACTA,363(4),669-675. |
| MLA | Wang, Zhuo,et al."Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate".INORGANICA CHIMICA ACTA 363.4(2010):669-675. |
入库方式： OAI收割
来源：化学研究所
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