Chitosan-mediated synthesis of mesoporous alpha-Fe2O3 nanoparticles and their applications in catalyzing selective oxidation of cyclohexane
文献类型：期刊论文
| 作者 | Huang ChangLiang; Zhang HongYe; Sun ZhenYu; Liu ZhiMin |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 53期号:7页码:1502-1508 |
| 关键词 | Chitosan Mesoporous Nanoparticles Alpha-fe2o3 Cyclohexane Oxidation |
| ISSN号 | 1674-7291 |
| DOI | 10.1007/s11426-010-4004-1 |
| 英文摘要 | This paper reports the chitosan-mediated synthesis of porous hematite nanoparticles with FeCl3 as the precursor via a hydrothermal approach at 160 degrees C. A series of porous chitosan/iron oxide hybrid nanoparticles were obtained via changing the ratio of chitosan to FeCl3, FeCl3 concentration and pH value of the reaction solution, and producing porous iron oxide nanoparticles after calcination. The as-prepared samples were characterized by means of X-ray diffraction, transmission electron microscopy, thermal gravimetric analysis, Fourier transform infrared, and N-2 sorption. The particle sizes of these metal oxides were less than 100 nm, and the pore sizes were in the range of 2-16 nm. It was demonstrated that chitosan played a key role in the formation of the porous structures. The resultant alpha-Fe2O3 nanoparticles were used as the support to immobilize Au or Pd nanoparticles, producing Au/alpha-Fe2O3 or Pd/alpha-Fe2O3 nanoparticles. The as-prepared alpha-Fe2O3 nanocatalyst exhibited high selectivity towards cyclohexanone and cyclohexanol for catalyzing cyclohexane oxidation with O-2 at 150 degrees C. |
| 语种 | 英语 |
| WOS记录号 | WOS:000280481500009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68867]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu ZhiMin |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang ChangLiang,Zhang HongYe,Sun ZhenYu,et al. Chitosan-mediated synthesis of mesoporous alpha-Fe2O3 nanoparticles and their applications in catalyzing selective oxidation of cyclohexane[J]. SCIENCE CHINA-CHEMISTRY,2010,53(7):1502-1508. |
| APA | Huang ChangLiang,Zhang HongYe,Sun ZhenYu,&Liu ZhiMin.(2010).Chitosan-mediated synthesis of mesoporous alpha-Fe2O3 nanoparticles and their applications in catalyzing selective oxidation of cyclohexane.SCIENCE CHINA-CHEMISTRY,53(7),1502-1508. |
| MLA | Huang ChangLiang,et al."Chitosan-mediated synthesis of mesoporous alpha-Fe2O3 nanoparticles and their applications in catalyzing selective oxidation of cyclohexane".SCIENCE CHINA-CHEMISTRY 53.7(2010):1502-1508. |
入库方式： OAI收割
来源：化学研究所
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