中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and characterization of a novel solid-solid phase change luminescence material

文献类型:期刊论文

作者Gu, Xiaohua2,3; Xi, Peng1; Cheng, Bowen1; Niu, Shuqing2
刊名POLYMER INTERNATIONAL
出版日期2010-06-01
卷号59期号:6页码:772-777
关键词Phase Change Poly(Ethylene Glycol) Rare Earth Luminescence
ISSN号0959-8103
DOI10.1002/pi.2787
英文摘要Because of the large energy storage and small temperature variation during the phase change process, phase change materials (PCMs) are attracting increasing attention. In this study, a novel solid-solid PCM was prepared by coordinating rare earth Eu(3+) ions to the carboxylate groups of a poly(ethylene glycol) (PEG) modified with two terephthalic acid groups. The structure and properties of the material were characterized using (1)H NMR, differential scanning calorimetry, infrared spectroscopy, gel permeation chromatograph and fluorescence spectroscopy. The coordination of Eu(3+) with the double-carboxylated PEG material significantly improved both the enthalpy value of the phase change material and its light-emitting properties. This paper describes the facile synthesis and characterization of a novel phase exchange luminescent Eu-PEG material. The light-emitting characterizations show that this modified PEG material has both good phase change properties and excellent luminescent properties. (C) 2010 Society of Chemical Industry
语种英语
WOS记录号WOS:000278343900010
出版者JOHN WILEY & SONS LTD
源URL[http://ir.iccas.ac.cn/handle/121111/68909]  
专题中国科学院化学研究所
通讯作者Xi, Peng
作者单位1.Tianjin Polytech Univ, Tianjin Municipal Key Lab Fiber Modificat & Funct, Tianjin 300160, Peoples R China
2.Qiqihar Univ, Coll Mech Engn, Qiqihar 161006, Peoples R China
3.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, CAS Key Lab Engn Plast,Joint Lab Polymer Sci & Ma, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Gu, Xiaohua,Xi, Peng,Cheng, Bowen,et al. Synthesis and characterization of a novel solid-solid phase change luminescence material[J]. POLYMER INTERNATIONAL,2010,59(6):772-777.
APA Gu, Xiaohua,Xi, Peng,Cheng, Bowen,&Niu, Shuqing.(2010).Synthesis and characterization of a novel solid-solid phase change luminescence material.POLYMER INTERNATIONAL,59(6),772-777.
MLA Gu, Xiaohua,et al."Synthesis and characterization of a novel solid-solid phase change luminescence material".POLYMER INTERNATIONAL 59.6(2010):772-777.

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来源:化学研究所

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