2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization
文献类型：期刊论文
| 作者 | Zhang, Min1,2; Zhang, Wenjuan1,2; Xiao, Tianpengfei1,2; Xiang, Jun-Feng1,2; Hao, Xiang1,2; Sun, Wen-Hua1,2,3
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| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
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| 出版日期 | 2010-04-01 |
| 卷号 | 320期号:1-2页码:92-96 |
| 关键词 | Iron(Ii) Complexes Ethylene Oligomerization 2-ethyl-ketimino-1 10-phenanthroline |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2010.01.009 |
| 英文摘要 | A series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1-L7) and their corresponding iron(II) chlorides (Fe1-Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (13) and (2-11(2,6-diethylphenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline} center dot FeCl(2) (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for alpha-olefins produced. Compared with other 2-imino-phenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed. (c) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000276011600014 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68919]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Nat Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Min,Zhang, Wenjuan,Xiao, Tianpengfei,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2010,320(1-2):92-96. |
| APA | Zhang, Min,Zhang, Wenjuan,Xiao, Tianpengfei,Xiang, Jun-Feng,Hao, Xiang,&Sun, Wen-Hua.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,320(1-2),92-96. |
| MLA | Zhang, Min,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 320.1-2(2010):92-96. |
入库方式： OAI收割
来源：化学研究所
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