中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Solvent-Induced Crystallization of PS-b-PEO-b-PS Block Copolymer Films

文献类型:期刊论文

作者Luo, Chunyan1,2; Han, Xia1,2; Gao, Ying3; Liu, Honglai1,2
刊名JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
出版日期2010
卷号49期号:3页码:440-453
关键词Block Copolymer Crystallization Dewetting Films Solvent Solvent-induced Substrate
ISSN号0022-2348
DOI10.1080/00222340903547380
英文摘要Solvent-induced crystallization and dewetting behaviors of polystyrene-b-poly (ethylene oxide)-b-polystyrene (PS-b-PEO-b-PS) block copolymer films deposited on three different substrates, silicon, mica, and carbon-coated mica have been studied by atomic force microscope (AFM). When the common solvent dichloromethane was used for annealing, the films on all three of the substrates exhibited dewetting behavior; the dendritic crystallization patterns were found in the dewetted regions for the films on silicon and mica substrates, while for the films on carbon-coated mica, no crystallization pattern appeared. According to the observation of the crystallization patterns formed in the films with different initial thicknesses, it is shown that the width of the dendritic branches decreases with the increase of film thickness and solvent annealing time. When the PS-selective solvent toluene was used for annealing, the dewetting process was absent, and the crystallization patterns were observed on the surface of the films on all three kinds of substrates.
语种英语
WOS记录号WOS:000277550300004
出版者TAYLOR & FRANCIS INC
源URL[http://ir.iccas.ac.cn/handle/121111/68925]  
专题中国科学院化学研究所
通讯作者Han, Xia
作者单位1.E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China
2.E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China
3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Luo, Chunyan,Han, Xia,Gao, Ying,et al. Solvent-Induced Crystallization of PS-b-PEO-b-PS Block Copolymer Films[J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,2010,49(3):440-453.
APA Luo, Chunyan,Han, Xia,Gao, Ying,&Liu, Honglai.(2010).Solvent-Induced Crystallization of PS-b-PEO-b-PS Block Copolymer Films.JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS,49(3),440-453.
MLA Luo, Chunyan,et al."Solvent-Induced Crystallization of PS-b-PEO-b-PS Block Copolymer Films".JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS 49.3(2010):440-453.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。