Iron(III) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: Synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization
文献类型：期刊论文
| 作者 | Hao, Peng1,2; Chen, Yanjun1,2; Xiao, Tianpengfei1,2; Sun, Wen-Hua1,2,3
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| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 695期号:1页码:90-95 |
| 关键词 | Ferric Complex 2-(Benzimidazole)-6-(1-aryliminoethyl)Pyridine Ethylene Oligomerization And Polymerization |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2009.09.032 |
| 英文摘要 | A series of iron(III) complexes ligated by 2-(benzimidazole)-6-(1-aryliminoethyl) pyridines was synthesized and examined by (1)H NMR, ESI-MS, IR spectroscopic, elemental analysis and X-ray photoelectron spectroscopy (XPS). Activated with methylaluminoxane (MAO), all ferric complexes exhibited good activities (up to 5.38 x 10(6) g mol (1)(Fe) h (1)) of ethylene oligomerization and polymerization, and resultant oligomers and polyethylene waxes showed high alpha-olefin feature, meanwhile the distribution of oligomers mostly resembled Schulz-Flory rules. The various reaction parameters were investigated in detail, and the less bulky and electron-withdrawing substituents of ligands could enhance the catalytic activities of their ferric complexes. The observations explain the cause for unstable activities performed by stored iron(II) complexes. (C) 2009 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000271661100014 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69027]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hao, Peng,Chen, Yanjun,Xiao, Tianpengfei,et al. Iron(III) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: Synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2010,695(1):90-95. |
| APA | Hao, Peng,Chen, Yanjun,Xiao, Tianpengfei,&Sun, Wen-Hua.(2010).Iron(III) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: Synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,695(1),90-95. |
| MLA | Hao, Peng,et al."Iron(III) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: Synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 695.1(2010):90-95. |
入库方式： OAI收割
来源：化学研究所
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