Influence of In Situ Compatibilization on In Situ Formation of Low-Density Polyethylene/Polyamide 6 Blends by Reactive Extrusion
文献类型：期刊论文
| 作者 | Fang, Hui1,2; Yang, Guisheng1,3 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2010-06-05 |
| 卷号 | 116期号:5页码:3027-3034 |
| 关键词 | In Situ Polymerization In Situ Compatibilization Reactive Extrusion Polyamide 6 Blend |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.31843 |
| 英文摘要 | Low-density polyethylene/polyamide 6 (LDPE/PA6) blends were in situ formed by reactive extrusion, in which in situ polymerization of e-caprolactam (CL) and in situ copolymerization of maleic anhydride grafted low-density polyethylene (LDPE-MA) and CL took place simultaneously. The latter reaction could be considered as in situ compatibilization, and the influence of in situ compatibilization on the morphologies, thermal properties, and rheological behaviors of the blends was investigated in this work. Scanning electron microscopy showed that the in situ compatibilization could dramatically reduce the dispersed phase sizes and narrow the size distribution. The thermal properties indicated that in differential scanning calorimetry (DSC) cooling scans, fractionated crystallization of the PA6 component was observed in all cases and was promoted with increasing the amount of LDPE-MA. The DSC second heating scans showed the in situ compatibilization could stimulate the formation of the less stable gamma-crystalline form of PA6 in the blends. Dynamic rheological experiments revealed the in situ compatibilization had enhanced the viscosity, storage modulus, and loss modulus of the blend and reduce the corresponding slope values of the storage modulus and loss modulus. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 116: 3027-3034, 2010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000276525400067 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69047]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China 2.Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Hui,Yang, Guisheng. Influence of In Situ Compatibilization on In Situ Formation of Low-Density Polyethylene/Polyamide 6 Blends by Reactive Extrusion[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,116(5):3027-3034. |
| APA | Fang, Hui,&Yang, Guisheng.(2010).Influence of In Situ Compatibilization on In Situ Formation of Low-Density Polyethylene/Polyamide 6 Blends by Reactive Extrusion.JOURNAL OF APPLIED POLYMER SCIENCE,116(5),3027-3034. |
| MLA | Fang, Hui,et al."Influence of In Situ Compatibilization on In Situ Formation of Low-Density Polyethylene/Polyamide 6 Blends by Reactive Extrusion".JOURNAL OF APPLIED POLYMER SCIENCE 116.5(2010):3027-3034. |
入库方式： OAI收割
来源：化学研究所
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