(Imido)vanadium(V)-alkyl, -alkylidene complexes exhibiting unique reactivity towards olefins and alcohols
文献类型:期刊论文
作者 | Nomura, Kotohiro1; Zhang, Wenjuan2 |
刊名 | CHEMICAL SCIENCE
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出版日期 | 2010 |
卷号 | 1期号:2页码:161-173 |
ISSN号 | 2041-6520 |
DOI | 10.1039/c0sc00163e |
英文摘要 | This minireview introduces recent results in the synthesis of a series of (imido) vanadium(V)-alkyl complexes, and some reactions with alcohols (phenols) that are proposed to proceed via intermediates involving coordination of the alcohols (phenols). (Imido) vanadium(V)-alkylidene complexes, prepared by a-hydrogen elimination in the presence of a neutral donor ligand (PMe3, etc.), exhibited high activity for ring-opening metathesis polymerisation of cyclic olefins (norbornene) even at high temperature; these are promising for olefin metathesis by vanadium complex catalysts. |
语种 | 英语 |
WOS记录号 | WOS:000281436100002 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.iccas.ac.cn/handle/121111/69101] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Nomura, Kotohiro |
作者单位 | 1.Tokyo Metropolitan Univ, Dept Chem, Tokyo 1920397, Japan 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Nomura, Kotohiro,Zhang, Wenjuan. (Imido)vanadium(V)-alkyl, -alkylidene complexes exhibiting unique reactivity towards olefins and alcohols[J]. CHEMICAL SCIENCE,2010,1(2):161-173. |
APA | Nomura, Kotohiro,&Zhang, Wenjuan.(2010).(Imido)vanadium(V)-alkyl, -alkylidene complexes exhibiting unique reactivity towards olefins and alcohols.CHEMICAL SCIENCE,1(2),161-173. |
MLA | Nomura, Kotohiro,et al."(Imido)vanadium(V)-alkyl, -alkylidene complexes exhibiting unique reactivity towards olefins and alcohols".CHEMICAL SCIENCE 1.2(2010):161-173. |
入库方式: OAI收割
来源:化学研究所
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