Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization
文献类型：期刊论文
| 作者 | Zhang, Zhichao1,2; Cui, Dongmei1; Trifonov, Alexander A.3 |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2010-06-01 |
| 期号 | 18页码:2861-2866 |
| 关键词 | Rare Earths Tridentate Ligands Polymerization |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.201000108 |
| 英文摘要 | A series of rare-earth metal alkyl complexes supported by a heteroscorpionate ligand were prepared and structurally characterized. X-ray diffraction analysis revealed that the heteroscorpionate ligand is face-capping on the rare-earth metal in k(3) mode, making the configuration of the afforded chalky! metal complexes similar to that of half-metallocenes. These complexes are capable of polymerizing methyl methacrylate, with the lutetium complex displaying the highest activity even at low temperature. The poly(methyl methacrylate) obtained is syndiotactically enriched with narrow molecular weight distribution. |
| 语种 | 英语 |
| WOS记录号 | WOS:000279975400035 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69119]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cui, Dongmei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia |
| 推荐引用方式 GB/T 7714 | Zhang, Zhichao,Cui, Dongmei,Trifonov, Alexander A.. Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010(18):2861-2866. |
| APA | Zhang, Zhichao,Cui, Dongmei,&Trifonov, Alexander A..(2010).Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(18),2861-2866. |
| MLA | Zhang, Zhichao,et al."Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .18(2010):2861-2866. |
入库方式： OAI收割
来源：化学研究所
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