Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water
文献类型：期刊论文
| 作者 | Wu, Suxiang; Fan, Honglei; Xie, Ye; Cheng, Yan; Wang, Qian; Zhang, Zhaofu; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:7页码:1215-1219 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c002553d |
| 英文摘要 | The CO2-water system has the potential to serve as a substitute for mineral acids for some reactions in acidic media. In this work, two reactions under hydrothermal conditions with and without CO2 were studied-the conversion of inulin to 5-hydroxymethylfurfural (5-HMF), and the hydrolysis of propylene oxide to 1,2-propanediol (1,2-PDO). The effects of CO2 pressure, reaction temperature and reactant concentration on the yield of 5-HMF and 1,2-PDO were examined. It was demonstrated that CO2 could increase the yields of 5-HMF and 1,2-PDO considerably under optimized conditions. The methods to prepare 5-HMF and 1,2-PDO are greener, in that conventional acids are not required and the solution is neutralized automatically after depressurization. |
| 语种 | 英语 |
| WOS记录号 | WOS:000279566300014 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69133]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, Suxiang |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Suxiang,Fan, Honglei,Xie, Ye,et al. Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water[J]. GREEN CHEMISTRY,2010,12(7):1215-1219. |
| APA | Wu, Suxiang.,Fan, Honglei.,Xie, Ye.,Cheng, Yan.,Wang, Qian.,...&Han, Buxing.(2010).Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water.GREEN CHEMISTRY,12(7),1215-1219. |
| MLA | Wu, Suxiang,et al."Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water".GREEN CHEMISTRY 12.7(2010):1215-1219. |
入库方式： OAI收割
来源：化学研究所
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