Synthesis of Bisazacalix[n]pyridines and Their Complexation with C-60 and C-70
文献类型：期刊论文
| 作者 | Zhang, Enxuan1; Wang, Dexian1; Huang, Zhitang1; Wang, Meixiang1,2 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 28期号:9页码:1690-1696 |
| 关键词 | Bisazacalix[n]Pyridine Fullerene Macrocyclic Molecule Complexation |
| ISSN号 | 1001-604X |
| 英文摘要 | Disulfane-linked bisazacalix[n]pyridines (n=4, 7) were synthesized for the first time using a macrocyclic fragment coupling approach followed by post-macrocyclization photoreaction with ethanethioic acid and hydrolysis under basic conditions. The bis-macrocyclic compounds acted as strong receptors to form 1 : 1 complex with C-60 and C-70, giving a binding constant (K-a(1: 1)) up to 107000 L.mol(-1). The cooperation of two mono-macrocyclic improved binding affinity to fullerenes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000282998700029 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69157]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dexian |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Tsinghua Univ, Key Lab Bioorgan Phosphorous Chem & Chem Biol, Minist Educ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Enxuan,Wang, Dexian,Huang, Zhitang,et al. Synthesis of Bisazacalix[n]pyridines and Their Complexation with C-60 and C-70[J]. CHINESE JOURNAL OF CHEMISTRY,2010,28(9):1690-1696. |
| APA | Zhang, Enxuan,Wang, Dexian,Huang, Zhitang,&Wang, Meixiang.(2010).Synthesis of Bisazacalix[n]pyridines and Their Complexation with C-60 and C-70.CHINESE JOURNAL OF CHEMISTRY,28(9),1690-1696. |
| MLA | Zhang, Enxuan,et al."Synthesis of Bisazacalix[n]pyridines and Their Complexation with C-60 and C-70".CHINESE JOURNAL OF CHEMISTRY 28.9(2010):1690-1696. |
入库方式： OAI收割
来源：化学研究所
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