Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks
文献类型：期刊论文
| 作者 | Zhou Yin-Xi; Liang Shu-Guang; Song Jin-Liang; Wu Tian-Bin; Hu Su-Qin; Liu Hui-Zhen; Jiang Tao; Han Bu-Xing |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2010-04-01 |
| 卷号 | 26期号:4页码:939-945 |
| 关键词 | Metal Organic Framework Coordination Polymer Transesterification Diethyl Carbonate Asymmetrical Organic Carbonate |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20100406 |
| 英文摘要 | Metal organic frameworks (MOFs) are a new class of materials that are formed by the copolymenzation of organic ligands with transition metals Because of their properties such as high surface areas. microporosity, and the ability to tune pore size, many applications have recently been developed in catalysis, separation, and gas storage We prepared MOFs by three different methods and characterized them with scanning electron microscopy (SEM). X-ray diffraction (XRD), and Infrared (IR) spectroscopy MOFs prepared via the three methods arc completely different in morphology and microstructure We demonstrate that the MOFs prepared via the "direct mixing" method are very effective heterogeneous catalyst for the transesterification of diethyl carbonate with alcohols to prepare organic carbonates We studied the effects of the amount of MOFs. the reaction MC, and the reaction temperature on product yield Asymmetric organic carbonates can be produced with moderate to high yields and 100% selectivity via the reaction of diethyl carbonate with aromatic, cyclic, heterocyclic, or aliphatic alcohols The solid catalyst can be recovered simply by centrifugation and reused for at least two cycles |
| 语种 | 英语 |
| WOS记录号 | WOS:000276958400021 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69177]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang Tao |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Yin-Xi,Liang Shu-Guang,Song Jin-Liang,et al. Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks[J]. ACTA PHYSICO-CHIMICA SINICA,2010,26(4):939-945. |
| APA | Zhou Yin-Xi.,Liang Shu-Guang.,Song Jin-Liang.,Wu Tian-Bin.,Hu Su-Qin.,...&Han Bu-Xing.(2010).Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks.ACTA PHYSICO-CHIMICA SINICA,26(4),939-945. |
| MLA | Zhou Yin-Xi,et al."Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks".ACTA PHYSICO-CHIMICA SINICA 26.4(2010):939-945. |
入库方式： OAI收割
来源：化学研究所
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