Self-assembled 3-D flower-shaped SnO2 nanostructures with improved electrochemical performance for lithium storage
文献类型:期刊论文
作者 | Yang, Rong1; Gu, Yingan1; Li, Yaoqi1; Zheng, Jie1; Li, Xingguo1,2 |
刊名 | ACTA MATERIALIA
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出版日期 | 2010-02-01 |
卷号 | 58期号:3页码:866-874 |
关键词 | Sno2 Crystal Growth Nanostructure Electrochemistry |
ISSN号 | 1359-6454 |
DOI | 10.1016/j.actamat.2009.10.001 |
英文摘要 | Flower-shaped SnO2 nanoplates were successfully synthesized via a simple hydrothermal treatment of a mixture of tin(II) dichloride dihydrate (SnCl2 center dot 2H(2)O) and sodium citrate (Na3C6H5O7 center dot 2H(2)O) in alkali solution. The obtained SnO2 nanoplates were less than 5 nm thick and self-assembled into flower-shaped nanostructures. The introduction of citrate was essential for the preparation of the SnO2 nanoplates. The nanoscale shape and self-assembled architecture of SnO2 nanoparticles were mainly controlled by the alkalinity of the solution. When the self-assembled SnO2 nanostructures were used as anode materials in Li-ion batteries, they exhibit a reversible capacity of 670 mA h g(-1) after 30 cycles and an average capacity fading of 0.95% per cycle after the second cycle. The good electrochemical performance of the SnO2 sample prepared via the hydrothermal synthesis indicates the possibility of fabricating specific self-assembled three-dimensional nanostructures for Li-ion batteries. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000274765600013 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/69181] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Xingguo |
作者单位 | 1.Peking Univ, BNLMS, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.Peking Univ, Coll Engn, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Rong,Gu, Yingan,Li, Yaoqi,et al. Self-assembled 3-D flower-shaped SnO2 nanostructures with improved electrochemical performance for lithium storage[J]. ACTA MATERIALIA,2010,58(3):866-874. |
APA | Yang, Rong,Gu, Yingan,Li, Yaoqi,Zheng, Jie,&Li, Xingguo.(2010).Self-assembled 3-D flower-shaped SnO2 nanostructures with improved electrochemical performance for lithium storage.ACTA MATERIALIA,58(3),866-874. |
MLA | Yang, Rong,et al."Self-assembled 3-D flower-shaped SnO2 nanostructures with improved electrochemical performance for lithium storage".ACTA MATERIALIA 58.3(2010):866-874. |
入库方式: OAI收割
来源:化学研究所
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