Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP
文献类型：期刊论文
| 作者 | Huang, Huahua; Niu, Hui; Dong, Jin Yong |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2010-12-15 |
| 卷号 | 48期号:24页码:5783-5789 |
| 关键词 | Atom Transfer Radical Polymerization (Atrp) Block Copolymers Chain End Functionalization Diblock Copolymer Polyolefins Polypropylene |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.24386 |
| 英文摘要 | This article demonstrates a facile and efficient method to combine olefin coordination polymerization with atom transfer radical polymerization (ATRP) for the synthesis of isotactic polypropylene (i PP) based functional diblock copolymers The chemistry involves a styryl capped i PP pre cursor prepared through the controlled consecutive chain transfer reaction first to 1 2 bis(4 vinylphenyl)ethane and then to hydrogen in propylene polymerization mediated by an isospecific metallocene catalyst The i PP precursor can be quantitatively transformed into i PP terminated with a 1 chlor oethylbezene group (i PP t Cl) by a straightforward hydro chlorination process using hydrogen chloride With the resultant i PP t Cl as a macroinitiator of ATRP methyl meth acrylate (MMA) polymerization was exemplified in the presence of CuBr/pentamethyldiethylenetriamine preparing i PP b-PMMA copolymers of different PMMA contents (c) 2010 Wiley Periodicals Inc J Polym Sci Part A Polym Chem 48 5783-5789 2010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000285485700017 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69213]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Niu, Hui |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Huahua,Niu, Hui,Dong, Jin Yong. Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2010,48(24):5783-5789. |
| APA | Huang, Huahua,Niu, Hui,&Dong, Jin Yong.(2010).Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,48(24),5783-5789. |
| MLA | Huang, Huahua,et al."Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 48.24(2010):5783-5789. |
入库方式： OAI收割
来源：化学研究所
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