Effect of film thickness, blending and undercoating on optical detection of nitroaromatics using fluorescent polymer films
文献类型：期刊论文
| 作者 | Wang, Zhaohui1; Wang, Zhi Yuan1; Ma, Jianjun2; Bock, Wojtek J.2; Ma, Dongge3 |
| 刊名 | POLYMER
 |
| 出版日期 | 2010-02-15 |
| 卷号 | 51期号:4页码:842-847 |
| 关键词 | Nitroaromatics Detection Fibre-optic Sensing Fluorescent Polymers |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2010.01.003 |
| 英文摘要 | In this work, using a fluorescent poly(phenylene ethynylene) containing the rigid pentiptycene and large cholesteryl ester pendent groups, the fluorescence quenching properties of the polymer thin films in response to vapor of 2,4-dinitrotulene (DNT) have been investigated by varying the film thickness, applying an undercoating and blending with another polar polymer. A significant change in fluorescence intensity (51% in 60 s) in response to DNT vapor exposure at ambient temperature was achieved when the polymer film coated on glass plate was about 2 nm in thickness. In comparison with the film of polymer alone, the film undercoated with (3-aminopropyl)triethoxysilane and the film of polymer blend containing a non-fluorescent polymer showed additional 18.5% (in 20-s exposure) and 18.7% (in 5-min exposure) decrease in fluorescence intensity, respectively. The use of polymer or polymer blend coated on optic-fiber tip for detection of DNT vapor has also been demonstrated. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000274679700003 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69233]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Zhi Yuan |
| 作者单位 | 1.Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada 2.Univ Quebec Outaouais, Dept Informat & Ingn, Gatineau, PQ J8X 3X7, Canada 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zhaohui,Wang, Zhi Yuan,Ma, Jianjun,et al. Effect of film thickness, blending and undercoating on optical detection of nitroaromatics using fluorescent polymer films[J]. POLYMER,2010,51(4):842-847. |
| APA | Wang, Zhaohui,Wang, Zhi Yuan,Ma, Jianjun,Bock, Wojtek J.,&Ma, Dongge.(2010).Effect of film thickness, blending and undercoating on optical detection of nitroaromatics using fluorescent polymer films.POLYMER,51(4),842-847. |
| MLA | Wang, Zhaohui,et al."Effect of film thickness, blending and undercoating on optical detection of nitroaromatics using fluorescent polymer films".POLYMER 51.4(2010):842-847. |
入库方式： OAI收割
来源：化学研究所
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