Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)
文献类型：期刊论文
| 作者 | Hong, Miao1,2; Pan, Li1; Li, Bai-Xiang1; Li, Yue-Sheng1 |
| 刊名 | POLYMER
 |
| 出版日期 | 2010-07-22 |
| 卷号 | 51期号:16页码:3636-3643 |
| 关键词 | Terpolymer Functional Polyolefin Compatibilizer |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2010.06.006 |
| 英文摘要 | Novel terpolymers containing ethylene, 1-hexene and dicyclopentadiene (DCPD) were synthesized using bis(beta-enaminoketonato)titanium catalysts [PhN=C(R(2))CHC(R(1))O](2)TiCl(2) (1a: R(1) = Ph, R(2) = CF(3); 1b: R(1) = CF(3), R(2) = CH(3)). In the presence of modified methylaluminoxane, these catalysts afforded terpolymers with a broad range of monomer compositions and unimodal molecular weight distributions. (13)C NMR spectra reveal the exclusive insertion manner of DCPD maintained under various reaction conditions. DSC results show the melting temperature and the glass transition temperature are very sensitive to the terpolymer composition and the morphology can be easily tuned from semicrystalline state to amorphous state. With ethylene/1-hexene/DCPD molar ratio about 67/28/5, the terpolymer exhibits low glass transition temperature (T(g) = -50 degrees C) and has a great potential to serve as polyolefin elastomer. Additionally, the terpolymer containing 4.3 mol% 1-hexene and 1.6 mol% DCPD was served as the "reactive intermediate polyolefin" for PCL graft reaction. The composition of graft copolymer was well controllable and high graft efficiency was observed. The microscopy studies in conjunction with the tensile tests revealed that PCL graft copolymer is the effective compatibilizer for polyethylene/polar polymer blends by improving the interfacial adhesion between separated phases. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000280263200006 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69253]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yue-Sheng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun Branch, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hong, Miao,Pan, Li,Li, Bai-Xiang,et al. Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)[J]. POLYMER,2010,51(16):3636-3643. |
| APA | Hong, Miao,Pan, Li,Li, Bai-Xiang,&Li, Yue-Sheng.(2010).Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone).POLYMER,51(16),3636-3643. |
| MLA | Hong, Miao,et al."Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)".POLYMER 51.16(2010):3636-3643. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。