Direct Experimental Evidence for the Priority of Flexible Ligand Skeleton in Asymmetric Friedel-Crafts Alkylation of Indole with Nitroalkenes
文献类型：期刊论文
| 作者 | Liu, Han2; Wang, Neng-Dong2; Du, Da-Ming1,2 |
| 刊名 | LETTERS IN ORGANIC CHEMISTRY
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 7期号:2页码:114-120 |
| 关键词 | Rigid Scaffold Flexible Scaffold Diphenylamine Dihydroacridine Bis(Oxazoline) Friedel-crafts Alkylation |
| ISSN号 | 1570-1786 |
| 英文摘要 | Direct experimental evidence for the priority of flexible ligand skeleton in asymmetric Friedel-Crafts alkylation was obtained through XRD analysis of flexible ligand/ZnCl(2) complex, as well as synthesis of dihydroacridine-linked bis(oxazoline) ligands with planar rigid scaffold. A transition state model without NH center dot center dot center dot pi interaction was proposed for the rigid ligands to interpret the inversion of absolute configuration. |
| 语种 | 英语 |
| WOS记录号 | WOS:000275168000006 |
| 出版者 | BENTHAM SCIENCE PUBL LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69259]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, Da-Ming |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China 2.Peking Univ, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Han,Wang, Neng-Dong,Du, Da-Ming. Direct Experimental Evidence for the Priority of Flexible Ligand Skeleton in Asymmetric Friedel-Crafts Alkylation of Indole with Nitroalkenes[J]. LETTERS IN ORGANIC CHEMISTRY,2010,7(2):114-120. |
| APA | Liu, Han,Wang, Neng-Dong,&Du, Da-Ming.(2010).Direct Experimental Evidence for the Priority of Flexible Ligand Skeleton in Asymmetric Friedel-Crafts Alkylation of Indole with Nitroalkenes.LETTERS IN ORGANIC CHEMISTRY,7(2),114-120. |
| MLA | Liu, Han,et al."Direct Experimental Evidence for the Priority of Flexible Ligand Skeleton in Asymmetric Friedel-Crafts Alkylation of Indole with Nitroalkenes".LETTERS IN ORGANIC CHEMISTRY 7.2(2010):114-120. |
入库方式： OAI收割
来源：化学研究所
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