The Role of Polymerizable Organophilic Clay During Preparing Polyethylene Nanocomposite via Filling Polymerization
文献类型：期刊论文
| 作者 | Ren, Changyi1,2; Du, Xiaohua1,2; Ma, Li1; Wang, Yanhui1; Tang, Tao1 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2010-08-05 |
| 卷号 | 117期号:3页码:1646-1657 |
| 关键词 | Clay Nanocomposites Polyethylene (Pe) Polymerization |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.32040 |
| 英文摘要 | Effect of polymerizable montmorillonites (P-MMTs) on the morphology of polyethylene/montmorillonites (PE/MMTs) nanocomposites during filling polymerization was studied. The microstructure analysis showed that the P-MMTs were more exfoliatable than non-polymerizable MMTs in the preparation of PE/MMTs nanocomposites. By examining the influence of the polymerization condition on the microstructure of the resultant nanocomposites, it was confirmed that the shear force formed by the mechanical stirring was the driving force of the exfoliation dispersion of MMT sheets during the filling polymerization. Comparatively, the shear force on MMT sheets might be increased due to strong interaction between PE chains linked to the surface of P-MMTs and the solvents molecules, which is the reason that polymerizable clay is more exfoliatable than nonpolymerizable clay. The copolymerization between polymerizable modifier and ethylene was confirmed by NMR measurements. Furthermore, the morphology of the resultant nanocomposites was influenced by the concentration of the dispersed PMMTs. The degree of exfoliation of the resultant nanocomposites at a relatively low concentration was higher than that at a high concentration. This is because of the multiscale organization of the organoclay dispersed in the organic medium. High exfoliation degree of MMTs and improved interaction between PE matrix and P-MMTs in PE/P-MMTs nanocomposites led to significant improvements in mechanical properties and barrier properties. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 1646-1657, 2010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000278571200049 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69289]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Changyi,Du, Xiaohua,Ma, Li,et al. The Role of Polymerizable Organophilic Clay During Preparing Polyethylene Nanocomposite via Filling Polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,117(3):1646-1657. |
| APA | Ren, Changyi,Du, Xiaohua,Ma, Li,Wang, Yanhui,&Tang, Tao.(2010).The Role of Polymerizable Organophilic Clay During Preparing Polyethylene Nanocomposite via Filling Polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,117(3),1646-1657. |
| MLA | Ren, Changyi,et al."The Role of Polymerizable Organophilic Clay During Preparing Polyethylene Nanocomposite via Filling Polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 117.3(2010):1646-1657. |
入库方式： OAI收割
来源：化学研究所
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