Study on the Anatase to Rutile Phase Transformation and Controlled Synthesis of Rutile Nanocrystals with the Assistance of Ionic Liquid
文献类型：期刊论文
| 作者 | Ding, Kunlun; Miao, Zhenjiang; Hu, Baoji; An, Guimin; Sun, Zhenyu; Han, Buxing; Liu, Zhimin |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2010-06-15 |
| 卷号 | 26期号:12页码:10294-10302 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/la100468e |
| 英文摘要 | We developed a route to synthesize rutile TiO(2) nanocrystals (NCs) with the assistance of 1-butyl-3-methylimidazolium chloride (bmim(+)Cl(-)). The phase transformation from anatase to rutile phase was investigated, and a simple model to describe the phase transformation process was proposed considering that the nucleation and growth of rutile phase were determined by the aggregation manner of anatase NCs and Ostwald ripening process, respectively. It was demonstrated that the surfactant-like nature of the IL used was crucial for controlling the crystallization process via controlling the aggregation manner of the NCs. The phase, shape, and size of TiO(2) NCs could be tuned by the controlling the operating conditions, such as temperature, solution acidity, and reactant concentration of the bmim(+)Cl(-)/TiCl(4)/H(2)O reaction system. Phase-pure rutile multipods and 1D nanorods with different sizes were controllably obtained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000278427600154 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69329]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhimin |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Kunlun,Miao, Zhenjiang,Hu, Baoji,et al. Study on the Anatase to Rutile Phase Transformation and Controlled Synthesis of Rutile Nanocrystals with the Assistance of Ionic Liquid[J]. LANGMUIR,2010,26(12):10294-10302. |
| APA | Ding, Kunlun.,Miao, Zhenjiang.,Hu, Baoji.,An, Guimin.,Sun, Zhenyu.,...&Liu, Zhimin.(2010).Study on the Anatase to Rutile Phase Transformation and Controlled Synthesis of Rutile Nanocrystals with the Assistance of Ionic Liquid.LANGMUIR,26(12),10294-10302. |
| MLA | Ding, Kunlun,et al."Study on the Anatase to Rutile Phase Transformation and Controlled Synthesis of Rutile Nanocrystals with the Assistance of Ionic Liquid".LANGMUIR 26.12(2010):10294-10302. |
入库方式： OAI收割
来源：化学研究所
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