Isolation by crystallization of translational isomers of a bistable donor-acceptor [2]catenane
文献类型：期刊论文
| 作者 | Wang, Cheng1; Olson, Mark A.1; Fang, Lei1; Benitez, Diego2; Tkatchouk, Ekaterina2; Basu, Subhadeep1; Basuray, Ashish N.1; Zhang, Deqing3; Zhu, Daoben3; Goddard, William A. |
| 刊名 | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
 |
| 出版日期 | 2010-08-10 |
| 卷号 | 107期号:32页码:13991-13996 |
| 关键词 | Mechanical Bond Formation Stereochemistry Template-directed Synthesis Structural Isomerism X-ray Crystallography |
| ISSN号 | 0027-8424 |
| DOI | 10.1073/pnas.1009302107 |
| 英文摘要 | The template-directed synthesis of a bistable donor-acceptor [2]catenane wherein both translational isomers-one in which a tetrathiafulvalene unit in a mechanically interlocked crown ether occupies the cavity of a cyclobis(paraquat-p-phenylene) ring and the other in which a 1,5-dioxynaphthalene unit in the crown ether resides inside the cavity of the tetracationic cyclophane-exist in equilibrium in solution, has led to the isolation and separation by hand picking of single crystals colored red and green, respectively. These two crystalline co-conformations have been characterized separately at both the molecular and supramolecular levels, and also by dynamic NMR spectroscopy in solution where there is compelling evidence that the mechanically interlocked molecules are present as a complex mixture of translational, configurational, and conformational isomers wherein the isomerization is best described as being a highly dynamic and adaptable phenomenon. |
| 语种 | 英语 |
| WOS记录号 | WOS:000280767700006 |
| 出版者 | NATL ACAD SCIENCES |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69333]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Stoddart, J. Fraser |
| 作者单位 | 1.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA 2.CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA 3.Chinese Acad Sci, Organ Solids Lab, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Cheng,Olson, Mark A.,Fang, Lei,et al. Isolation by crystallization of translational isomers of a bistable donor-acceptor [2]catenane[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2010,107(32):13991-13996. |
| APA | Wang, Cheng.,Olson, Mark A..,Fang, Lei.,Benitez, Diego.,Tkatchouk, Ekaterina.,...&Stoddart, J. Fraser.(2010).Isolation by crystallization of translational isomers of a bistable donor-acceptor [2]catenane.PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,107(32),13991-13996. |
| MLA | Wang, Cheng,et al."Isolation by crystallization of translational isomers of a bistable donor-acceptor [2]catenane".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 107.32(2010):13991-13996. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。