Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn
文献类型：期刊论文
| 作者 | Liu, Xiao-hui1; Bao, You-mei1; Tang, Xiu-lan2; Li, Yue-sheng1,2 |
| 刊名 | POLYMER
 |
| 出版日期 | 2010-06-07 |
| 卷号 | 51期号:13页码:2857-2863 |
| 关键词 | Hyperbranched Self-condensing Vinyl Polymerization (Scvp) Poly(Epsilon-caprolactone) |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2010.04.034 |
| 英文摘要 | A facile self-condensing vinyl polymerization (SCVP) system, the combination of glycidyl methacrylate, Cp2TiCl2 and Zn, has been firstly used to prepare novel hyperbranched polymers, consisting of vinyl polymers as the backbone, and cyclic ester polymers (poly(c-caprolactone) or poly(L-lactide)) as the side chains. The polymerizations are initiated by the epoxide radical ring-opening catalyzed by Cp2Ti(III)Cl which is generated in situ via the reaction of Cp2TiCl2 with Zn. The key to success is that the polymerizations can proceed concurrently via two dissimilar chemistries possessing the opposite active initiating species, including ring-opening polymerization (ROP) and controlled/living radical polymerization (CRP). We have demonstrated that this facile one-step polymerization technique can be applied successfully to prepare highly branched polymers with a multiplicity of end reactive functionalities including Ti alkoxide, hydroxyl and vinyl functional groups. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000279158800008 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69343]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yue-sheng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Yanshan Univ, Coll Environm & Chem Engn, Qinhuangdao 066004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiao-hui,Bao, You-mei,Tang, Xiu-lan,et al. Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn[J]. POLYMER,2010,51(13):2857-2863. |
| APA | Liu, Xiao-hui,Bao, You-mei,Tang, Xiu-lan,&Li, Yue-sheng.(2010).Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn.POLYMER,51(13),2857-2863. |
| MLA | Liu, Xiao-hui,et al."Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn".POLYMER 51.13(2010):2857-2863. |
入库方式： OAI收割
来源：化学研究所
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