Formate-Based Magnetic Metal-Organic Frameworks Templated by Protonated Amines
文献类型：期刊论文
| 作者 | Wang, Zheming1; Hu, Keli1; Gao, Song1; Kobayashi, Hayao2 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2010-04-06 |
| 卷号 | 22期号:13页码:1526-1533 |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.200904438 |
| 英文摘要 | A systematic study has been carried out on the 3d divalent metal formate 3D magnetic frameworks templated by protonated amines, and the achievements have revealed that metal formate frameworks are very malleable, and their structures depend on the size, shape, charge, and hydrogen bonding geometries of the templating cations. Six kinds of metal formate frameworks have been created. They are chiral frameworks with a (4(9). 6(6)) topology, perovskite ones with a (4(12). 6(3)) topology, bi-nodal frameworks of (4(12) . 6(3))(4(9) . 6(6))(n) (n = 1, 2, 3) topologies, and porous diamond frameworks with 6(6) topology. These materials display promising and abundant magnetic, dielectric, porous, and optical properties and the possible combination of them. Therefore, they are of great interest for the study of molecule-based materials. It has been demonstrated that formate, being the smallest and simplest carboxylate, cheap and with low toxicity, thus more biocompatible and environmentally friendly, and having been more or less ignored, will find an important role in the construction of molecule-based materials and provide new materials with interesting properties. |
| 语种 | 英语 |
| WOS记录号 | WOS:000276737700013 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69361]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Zheming |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Nihon Univ, Coll Humanities & Sci, Dept Chem, Setagaya Ku, Tokyo 1568550, Japan |
| 推荐引用方式 GB/T 7714 | Wang, Zheming,Hu, Keli,Gao, Song,et al. Formate-Based Magnetic Metal-Organic Frameworks Templated by Protonated Amines[J]. ADVANCED MATERIALS,2010,22(13):1526-1533. |
| APA | Wang, Zheming,Hu, Keli,Gao, Song,&Kobayashi, Hayao.(2010).Formate-Based Magnetic Metal-Organic Frameworks Templated by Protonated Amines.ADVANCED MATERIALS,22(13),1526-1533. |
| MLA | Wang, Zheming,et al."Formate-Based Magnetic Metal-Organic Frameworks Templated by Protonated Amines".ADVANCED MATERIALS 22.13(2010):1526-1533. |
入库方式： OAI收割
来源：化学研究所
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