H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra
文献类型：期刊论文
| 作者 | Cong, Rihong; Yang, Tao; Li, Hongmei; Liao, Fuhui; Wang, Yingxia; Lin, Jianhua |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2010-04-01 |
| 期号 | 11页码:1703-1709 |
| 关键词 | Borates Indium X-ray Diffraction Network Structures Hydrogen Bonds |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200901078 |
| 英文摘要 | H2InB5O10, a new hydrated indium pentaborate, was prepared by the boric acid flux method and characterized by IR, solid-state B-11 MAS NMR and H-1 CRAMPS NMR spectroscopy. Its structure was determined by powder X-ray diffraction and refined by Rietveld analysis. H2InB5O10 crystallizes in the monoclinic space group C2. The structure features a new 2D tetrahedrally four-connected borate network constructed from a new pentaborate fundamental building block, B5O14. The 2D borate network is formed by two 6(3) borate layers linked by additional BO4 groups in a spiro-5 mode and then combines with InO6 octahedra to give rise to the 3D structure of H2InB5O10. The strong hydrogen bonds that cross-link oxygen atoms of additional BO4 groups between the borate layers help to stabilize the borate network. |
| 语种 | 英语 |
| WOS记录号 | WOS:000277210400016 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69439]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yingxia |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cong, Rihong,Yang, Tao,Li, Hongmei,et al. H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010(11):1703-1709. |
| APA | Cong, Rihong,Yang, Tao,Li, Hongmei,Liao, Fuhui,Wang, Yingxia,&Lin, Jianhua.(2010).H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(11),1703-1709. |
| MLA | Cong, Rihong,et al."H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .11(2010):1703-1709. |
入库方式： OAI收割
来源：化学研究所
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