Synthesis and Properties of Poly(trimethylene terephthalate-co-2-methyl-ethylene terephthalate) Random Copolyesters
文献类型：期刊论文
| 作者 | Wu, Fangjuan1,2; Yang, Guisheng1,3 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2010-06-15 |
| 卷号 | 116期号:6页码:3419-3426 |
| 关键词 | Poly(Trimethylene Terephthalate) Poly(2-methyl-ethylene Terephthalate) Copolymerization Copolyesters 1 2-propanediol |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.31858 |
| 英文摘要 | Poly(trimethylene terephthalate-co-2-methylethylene terephthalate) random copolymers of various compositions were synthesized via traditional two-step polycondensation by incorporating of 1,2-propanediol. The molar composition of trimethylene terephthalate and 2-methyl-ethylene terephthalate units and chemical structure were confirmed by means of (1)H-NMR and Fourier transform infrared. The thermal properties of the copolyesters were evaluated by DSC and TGA. As far as the thermal properties is concerned, the main effect of incorporation of 1,2-propanediol was a lowering in the melting temperature, and an increment of glass transition temperature compared to homopolymer PTT. Due to the effect of the lateral methyl groups in the polymeric chain, the thermal stability is slightly decreased as the amount of the MET units is increased. Furthermore, the crystals of PTT/MET copolyesters were observed by hot-stage optical polarizing microscopy at the indicated crystallization temperatures. As expected, the incorporation of MET units in the polymer chain of PTT was found to decrease the dimension of the crystals. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 116: 3419-3426, 2010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000276710000037 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69653]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Fangjuan,Yang, Guisheng. Synthesis and Properties of Poly(trimethylene terephthalate-co-2-methyl-ethylene terephthalate) Random Copolyesters[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,116(6):3419-3426. |
| APA | Wu, Fangjuan,&Yang, Guisheng.(2010).Synthesis and Properties of Poly(trimethylene terephthalate-co-2-methyl-ethylene terephthalate) Random Copolyesters.JOURNAL OF APPLIED POLYMER SCIENCE,116(6),3419-3426. |
| MLA | Wu, Fangjuan,et al."Synthesis and Properties of Poly(trimethylene terephthalate-co-2-methyl-ethylene terephthalate) Random Copolyesters".JOURNAL OF APPLIED POLYMER SCIENCE 116.6(2010):3419-3426. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。