Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate
文献类型：期刊论文
| 作者 | Liang, Lei1; Rao, Guodong1; Sun, Hao-Ling2; Zhang, Jun-Long1 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2010-10-04 |
| 卷号 | 352期号:14-15页码:2371-2377 |
| 关键词 | Aerobic Oxidation Copper Catalysis Intermediates Primary Alcohols |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201000456 |
| 英文摘要 | We have developed a new protocol involving the "copper(II) chloride-cesium carbonate" system for the aerobic oxidation of primary alcohols. Cesium carbonates and the solvents such as toluene and 1,2-dichloroethane play important roles to form a catalytically active intermediate containing a mu-hydroxyl-bridged trinuclear copper moiety (complex 1). From the X-ray crystal structure of complex 1, an electrostatic interaction between chloride anions and cesium cations was observed, which stimulated us to understand the roles of cesium carbonate in this reaction as a base, stabilizing and "solvating" intermediates in toluene and 1,2-dichloroethane. |
| 语种 | 英语 |
| WOS记录号 | WOS:000284003100004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69715]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Jun-Long |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Lei,Rao, Guodong,Sun, Hao-Ling,et al. Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(14-15):2371-2377. |
| APA | Liang, Lei,Rao, Guodong,Sun, Hao-Ling,&Zhang, Jun-Long.(2010).Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate.ADVANCED SYNTHESIS & CATALYSIS,352(14-15),2371-2377. |
| MLA | Liang, Lei,et al."Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate".ADVANCED SYNTHESIS & CATALYSIS 352.14-15(2010):2371-2377. |
入库方式： OAI收割
来源：化学研究所
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