Development of Diphenylamine-Linked Bis(imidazoline) Ligands and Their Application in Asymmetric Friedel-Crafts Alkylation of Indole Derivatives with Nitroalkenes
文献类型：期刊论文
| 作者 | Liu, Han2; Du, Da-Ming1,2 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 352期号:7页码:1113-1118 |
| 关键词 | Asymmetric Catalysis Bis(Imidazoline)s Diphenylamine Friedel-crafts Alkylation Indoles Nitroalkenes |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201000111 |
| 英文摘要 | The new diphenylamine-linked bis(imidazoline) ligands were prepared through Kelly-You's imidazoline formation procedure mediated by Hendrickson's reagent in good yields. The novel ligands were tested in the asymmetric Friedel Crafts alkylation of indole derivatives with nitroalkenes. In most cases, good yields (up to 97%) and excellent enantioselectivities (up to 98%) can be achieved. The optimized bis(imidazoline) ligand with trans-diphenyl substitution on the imidazoline ring gave better enantioselectivity than the corresponding bis(oxazoline) ligand. |
| 语种 | 英语 |
| WOS记录号 | WOS:000277974100004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69723]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, Da-Ming |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China 2.Peking Univ, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Han,Du, Da-Ming. Development of Diphenylamine-Linked Bis(imidazoline) Ligands and Their Application in Asymmetric Friedel-Crafts Alkylation of Indole Derivatives with Nitroalkenes[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(7):1113-1118. |
| APA | Liu, Han,&Du, Da-Ming.(2010).Development of Diphenylamine-Linked Bis(imidazoline) Ligands and Their Application in Asymmetric Friedel-Crafts Alkylation of Indole Derivatives with Nitroalkenes.ADVANCED SYNTHESIS & CATALYSIS,352(7),1113-1118. |
| MLA | Liu, Han,et al."Development of Diphenylamine-Linked Bis(imidazoline) Ligands and Their Application in Asymmetric Friedel-Crafts Alkylation of Indole Derivatives with Nitroalkenes".ADVANCED SYNTHESIS & CATALYSIS 352.7(2010):1113-1118. |
入库方式： OAI收割
来源：化学研究所
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