Study on the Oriented Recrystallization of Carbon-Coated Polyethylene Oriented Ultrathin Films
文献类型：期刊论文
| 作者 | Chang, Haibo2,3; Guo, Qipeng4; Shen, Deyan2; Li, Lin2; Qiti, Zhaobin1; Wang, Feng1; Yan, Shouke1,2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2010-10-21 |
| 卷号 | 114期号:41页码:13104-13109 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp106995f |
| 英文摘要 | It is confirmed that a layer of vacuum-evaporated carbon on the surface of a preoriented ultrathin polymer film can lead to an oriented recrystallization of the polymer film. This has been attributed to a strong fixing effect of vacuum-evaporated carbon layer on the film surface of the polymer. To study the origin of the strong fixing effect of vacuum-evaporated carbon layer on the polymer films, the melting and recrystallization behaviors of the preoriented ultrathin PE film with a vacuum-evaporated carbon layer were studied by using atomic force microscopy, electron diffraction, Fourier transform infrared spectroscopy, and Raman spectroscopy. We found that there exists some extent of chain orientation of carbon-coated polyethylene (PE) preoriented ultrathin film above its melting temperature. These oriented PE chain sequences act as nucleation sites and induce the Oriented recrystallization of preoriented PE film from melt. Raman spectroscopy results suggest that new carbon-carbon bonds between the carbon layer and the oriented PE film are created during the process of vacuum carbon evaporation. As a result, some of the PE chain stems are fixed to the coated carbon substrate via covalent bond. Such a bonding has retarded the relaxation of the PE chains at the spot and, therefore, preserves the original orientation of the PE stems at high temperature, which in turn derives the recrystallization of the PE chains in an oriented structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000282855100009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69751]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Feng |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Henan Univ, Coll Chem & Chem Engn, Kaifeng 475001, Peoples R China 4.Deakin Univ, Ctr Mat & Fibre Innovat, Geelong, Vic 3271, Australia |
| 推荐引用方式 GB/T 7714 | Chang, Haibo,Guo, Qipeng,Shen, Deyan,et al. Study on the Oriented Recrystallization of Carbon-Coated Polyethylene Oriented Ultrathin Films[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2010,114(41):13104-13109. |
| APA | Chang, Haibo.,Guo, Qipeng.,Shen, Deyan.,Li, Lin.,Qiti, Zhaobin.,...&Yan, Shouke.(2010).Study on the Oriented Recrystallization of Carbon-Coated Polyethylene Oriented Ultrathin Films.JOURNAL OF PHYSICAL CHEMISTRY B,114(41),13104-13109. |
| MLA | Chang, Haibo,et al."Study on the Oriented Recrystallization of Carbon-Coated Polyethylene Oriented Ultrathin Films".JOURNAL OF PHYSICAL CHEMISTRY B 114.41(2010):13104-13109. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。