Effects of Inorganic and Organic Salts on Aggregation Behavior of Cationic Gemini Surfactants
文献类型：期刊论文
| 作者 | Yu, Defeng2; Huang, Xu2; Deng, Manli2; Lin, Yiyang1; Jiang, Lingxiang1; Huang, Jianbin1; Wang, Yilin2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2010-11-25 |
| 卷号 | 114期号:46页码:14955-14964 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp106031d |
| 英文摘要 | All salts studied effectively reduce critical micelle concentration(CMC) values of the cationic gemini surfactants. The ability to promote the surfactant aggregation decreases in the order of C(6)H(5)COONa > p-C(6)H(4)(COONa)(2) > Na(2)SO(4) NaCl. Moreover, only C(6)H(5)COONa distinctly reduces both the CMC values and the surface tension at CMC. For 12-4-12 solution, the penetration of C(6)H(5)COO(-) anions and charge neutralization induce a morphology change from micelles to vesicles, whereas the other salts only slightly increase the sizes of micelles. The 12-4(OH)(2)-12 solution changes from the micelle/vesicle coexistence to vesicles with the addition of C(6)H(5)COONa, whereas the other salts transfer the 12-4(OH)(2)-12 solution from the micelle/vesicle coexistence to micelles. As compared with 12-4-12, the two hydroxyls in the spacer of 12-4(OH)(2)-12 promote the micellization of 12-4(OH)(2)-12 and reduce the amounts of C(6)H(5)COONa required to induce the micelle-to-vesicle transition. |
| 语种 | 英语 |
| WOS记录号 | WOS:000284287700020 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69793]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Jianbin |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid & Intetface Sci, Inst Chem, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Defeng,Huang, Xu,Deng, Manli,et al. Effects of Inorganic and Organic Salts on Aggregation Behavior of Cationic Gemini Surfactants[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2010,114(46):14955-14964. |
| APA | Yu, Defeng.,Huang, Xu.,Deng, Manli.,Lin, Yiyang.,Jiang, Lingxiang.,...&Wang, Yilin.(2010).Effects of Inorganic and Organic Salts on Aggregation Behavior of Cationic Gemini Surfactants.JOURNAL OF PHYSICAL CHEMISTRY B,114(46),14955-14964. |
| MLA | Yu, Defeng,et al."Effects of Inorganic and Organic Salts on Aggregation Behavior of Cationic Gemini Surfactants".JOURNAL OF PHYSICAL CHEMISTRY B 114.46(2010):14955-14964. |
入库方式： OAI收割
来源：化学研究所
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