Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region
文献类型：期刊论文
| 作者 | Gerones, Mariana1; Erben, Mauricio F.1; Ge, Maofa3; Cavasso Filho, Reinaldo L.4; Romano, Rosana M.1; Della Vedova, Carlos O.1,2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2010-08-12 |
| 卷号 | 114期号:31页码:8049-8055 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp102179w |
| 英文摘要 | The simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000280523500004 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69833]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Erben, Mauricio F. |
| 作者单位 | 1.Univ Nacl La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR CONICET UNLP, RA-1900 La Plata, Buenos Aires, Argentina 2.UNLP CIC CONICET, LaSeISiC, RA-1903 Gonnet, Argentina 3.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Inst Chem, Beijing 100080, Peoples R China 4.Univ Fed ABC, BR-09090400 Sao Paulo, Brazil |
| 推荐引用方式 GB/T 7714 | Gerones, Mariana,Erben, Mauricio F.,Ge, Maofa,et al. Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2010,114(31):8049-8055. |
| APA | Gerones, Mariana,Erben, Mauricio F.,Ge, Maofa,Cavasso Filho, Reinaldo L.,Romano, Rosana M.,&Della Vedova, Carlos O..(2010).Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region.JOURNAL OF PHYSICAL CHEMISTRY A,114(31),8049-8055. |
| MLA | Gerones, Mariana,et al."Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region".JOURNAL OF PHYSICAL CHEMISTRY A 114.31(2010):8049-8055. |
入库方式： OAI收割
来源：化学研究所
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