Preparation and Characterization of LiBF4 by Gradient Heating Dehydration
文献类型：期刊论文
| 作者 | Zhou Yuan1; Zhang Xinyue1,2,3; Nian Hongen1; Pang Yuna1,2; Wang Hongbin1,2 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2010-07-28 |
| 卷号 | 68期号:14页码:1399-1403 |
| 关键词 | Libf4 Electrolyte Lithium-ion Battery Lithium Salt Aqueous Solution Process |
| ISSN号 | 0567-7351 |
| 英文摘要 | LiBF4 was prepared via aqueous solution process and its properties were examined by X-ray diffraction (XRD), IR, and thermogravimetry and differential thermogravimetry (TG-DTG). H3BO3, HF and Li2CO3 were used as starting materials to prepare LiBF4 solution, followed by concentrating, crystallizing and dehydrating to obtain LiBF4. The incomplete dehydration caused by traditional rapid heating was avoided through gradient heating dehydration. The obtained LiBF4 crystal belongs to the hexagonal system with space group P3(1)2(1), confirmed by its XRD spectrum which conformed to powder diffraction file (PDF) card 00-040-1431. The infrared absorption bands of the obtained LiBF4 were observed, one band located at 1050 cm(-1), and splitted off two bands which are located at 1055 and 1038 cm(-1); the other band located at 650 cm(-1); attributed to nu(3) (as) vibration and delta(3) (s) vibration, respectively. In TG-DTG spectrum, a weak decomposition peak was observed at 341.31 K and a strong decomposition peak appeared at 516.48 K, the weight loss rate was 72.33%. The decomposition was regarded as the LiBF4 decomposed into LiF and BF3. |
| 语种 | 英语 |
| WOS记录号 | WOS:000281685100009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69861]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou Yuan |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Yuan,Zhang Xinyue,Nian Hongen,et al. Preparation and Characterization of LiBF4 by Gradient Heating Dehydration[J]. ACTA CHIMICA SINICA,2010,68(14):1399-1403. |
| APA | Zhou Yuan,Zhang Xinyue,Nian Hongen,Pang Yuna,&Wang Hongbin.(2010).Preparation and Characterization of LiBF4 by Gradient Heating Dehydration.ACTA CHIMICA SINICA,68(14),1399-1403. |
| MLA | Zhou Yuan,et al."Preparation and Characterization of LiBF4 by Gradient Heating Dehydration".ACTA CHIMICA SINICA 68.14(2010):1399-1403. |
入库方式： OAI收割
来源：化学研究所
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