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Memory Effects of Diblock Copolymer Brushes and Mixed Brushes

文献类型:期刊论文

作者Wang, Jiafang1,2; Mueller, Marcus1
刊名LANGMUIR
出版日期2010-01-19
卷号26期号:2页码:1291-1303
ISSN号0743-7463
DOI10.1021/la902438e
英文摘要Memory effects of microphase segregation in diblock copolymer brushes and binary mixed homopolymer brushes exposed to solvents of different quality and selectivity are studied using Single-Cliain-in-Mean-Field (SCMF) simulations. We gauge these memory effects by a fluctuation memory measure, reflecting the correlation between the quenched fluctuations of grafting points and the microphase-separated morphology, and a domain memory measure, quantifying the correlation between Surface morphologies during cyclic exposure to different solvents. The fluctuation and domain memory measures are closely correlated, and both of them have their root in the broken translational symmetry of the distribution of grafting points. They become stronger upon increasing the fluctuations of the grafting points. The effects of solvent quality and selectivity, grafting density, and composition of brushes on the memory measures are discussed.
语种英语
WOS记录号WOS:000273403400093
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/69969]  
专题中国科学院化学研究所
通讯作者Wang, Jiafang
作者单位1.Univ Gottingen, Inst Theoret Phys, D-37077 Gottingen, Germany
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Wang, Jiafang,Mueller, Marcus. Memory Effects of Diblock Copolymer Brushes and Mixed Brushes[J]. LANGMUIR,2010,26(2):1291-1303.
APA Wang, Jiafang,&Mueller, Marcus.(2010).Memory Effects of Diblock Copolymer Brushes and Mixed Brushes.LANGMUIR,26(2),1291-1303.
MLA Wang, Jiafang,et al."Memory Effects of Diblock Copolymer Brushes and Mixed Brushes".LANGMUIR 26.2(2010):1291-1303.

入库方式: OAI收割

来源:化学研究所

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