Immobilization of Pd nanoparticles with functional ionic liquid grafted onto cross-linked polymer for solvent-free Heck reaction
文献类型：期刊论文
| 作者 | Liu, Gang; Hou, Minqiang; Song, Jiyuan; Jiang, Tao; Fan, Honglei; Zhang, Zhaofu; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:1页码:65-69 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/b913182e |
| 英文摘要 | 1-Aminoethyl-3-vinylimidazolium bromide ([VAIM]Br) grafted on the cross-linked polymer polydivinylbenzene (PDVB) was synthesized. The copolymers were used as a support to immobilize palladium nanoparticles. The catalyst was characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric (TG) analysis, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the copolymer-supported Pd nanoparticles for the Heck arylation of olefins with different aryl iodides was studied under solvent-free conditions. The results demonstrated that the catalyst was very active and stable under solvent-free conditions, and could be reused after simple separation. The reason for the high activity and stability of the catalyst is discussed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000273576000010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/69979]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Gang,Hou, Minqiang,Song, Jiyuan,et al. Immobilization of Pd nanoparticles with functional ionic liquid grafted onto cross-linked polymer for solvent-free Heck reaction[J]. GREEN CHEMISTRY,2010,12(1):65-69. |
| APA | Liu, Gang.,Hou, Minqiang.,Song, Jiyuan.,Jiang, Tao.,Fan, Honglei.,...&Han, Buxing.(2010).Immobilization of Pd nanoparticles with functional ionic liquid grafted onto cross-linked polymer for solvent-free Heck reaction.GREEN CHEMISTRY,12(1),65-69. |
| MLA | Liu, Gang,et al."Immobilization of Pd nanoparticles with functional ionic liquid grafted onto cross-linked polymer for solvent-free Heck reaction".GREEN CHEMISTRY 12.1(2010):65-69. |
入库方式： OAI收割
来源：化学研究所
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