Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors
文献类型：期刊论文
| 作者 | Gao, Xike1; Di, Chong-an2; Hu, Yunbin1; Yang, Xiaodi3; Fan, Hongyu1; Zhang, Feng1; Liu, Yunqi2; Li, Hongxiang1; Zhu, Daoben1,2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2010-03-24 |
| 卷号 | 132期号:11页码:3697-+ |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja910667y |
| 英文摘要 | A new class of n-type semiconductors for organic thin film transistors (OTFTs), based on core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups, is reported. The first two representatives of these species, derived from long branched N-alkyl chains, have been successfully used as active layers for high-performance, ambient-stable, solution-processed n-channel OTFTs. Their bottom-gate top-contact devices fabricated by spin-coating methods exhibit high electron mobilities of up to 0.51 cm(2) V(-1) s(-1) with current on/off ratios of 10(5)-10(7), and small threshold voltages below 10 V under ambient conditions. As this class of n-type organic semiconductors has relatively low-lying LUMO levels and good film-formation ability, they also displayed good environmental stability even with prolonged exposure to ambient air. Both the device performance and the ambient stability are among the best for n-channel OTFTs reported to date. |
| 语种 | 英语 |
| WOS记录号 | WOS:000275868700027 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70065]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Xike |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, Mat Sci Lab, Shanghai 200032, Peoples R China 2.CAS, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Xike,Di, Chong-an,Hu, Yunbin,et al. Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(11):3697-+. |
| APA | Gao, Xike.,Di, Chong-an.,Hu, Yunbin.,Yang, Xiaodi.,Fan, Hongyu.,...&Zhu, Daoben.(2010).Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(11),3697-+. |
| MLA | Gao, Xike,et al."Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.11(2010):3697-+. |
入库方式： OAI收割
来源：化学研究所
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