Formation of nanotubes and secondary assemblies of cyclodextrins induced by BBOT
文献类型：期刊论文
| 作者 | Zhang JingJing; Shen XingHai1; Wu AiHua; Zhang ChunFen; Chen QingDe; Gao HongCheng |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 53期号:9页码:2019-2025 |
| 关键词 | Bbot Cyclodextrin Nanotube Secondary Assembly |
| ISSN号 | 1674-7291 |
| DOI | 10.1007/s11426-010-4071-3 |
| 英文摘要 | The study of cyclodextrin nanotubes is a significant topic among the self-assembly behaviors of cyclodextrins. We report herein the interaction of 2,5-bis(5'-tert-butyl-2-benzoxazoyl)thiophene (BBOT) with alpha-, beta-, gamma-cyclodextrins (CDs). It has been discovered that the reaction patterns of BBOT with CDs are remarkably different. beta-CD forms a simple inclusion complex with BBOT in a stoichiometry of 1:2 (guest:host). beta-CD forms a 1:1 inclusion complex with BBOT at its low concentration. At higher concentration of BBOT, the nanotube and secondary assembly of beta-CD are formed. As for gamma-CD, the nanotube and secondary assembly are formed within the whole concentration range of BBOT studied. The structure of gamma-CD nanotubes is different from that of beta-CD nanotubes to a certain extent. |
| 语种 | 英语 |
| WOS记录号 | WOS:000282171900028 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70071]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shen XingHai |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Radiochem & Radiat Chem Key Lab Fundamental Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang JingJing,Shen XingHai,Wu AiHua,et al. Formation of nanotubes and secondary assemblies of cyclodextrins induced by BBOT[J]. SCIENCE CHINA-CHEMISTRY,2010,53(9):2019-2025. |
| APA | Zhang JingJing,Shen XingHai,Wu AiHua,Zhang ChunFen,Chen QingDe,&Gao HongCheng.(2010).Formation of nanotubes and secondary assemblies of cyclodextrins induced by BBOT.SCIENCE CHINA-CHEMISTRY,53(9),2019-2025. |
| MLA | Zhang JingJing,et al."Formation of nanotubes and secondary assemblies of cyclodextrins induced by BBOT".SCIENCE CHINA-CHEMISTRY 53.9(2010):2019-2025. |
入库方式： OAI收割
来源：化学研究所
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