Water-Soluble Triply-Responsive Homopolymers of N,N-Dimethylaminoethyl methacrylate with a Terminal Azobenzene Moiety
文献类型：期刊论文
| 作者 | Tang, Xinde1,2; Liang, Xiaochao1; Gao, Longcheng2; Fan, Xinghe2; Zhou, Qifeng2 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2010-06-15 |
| 卷号 | 48期号:12页码:2564-2570 |
| 关键词 | Atom Transfer Radical Polymerization (Atrp) Azobenzene Single-electron Transfer Living Radical Polymerization Azo Polymers Lower Critical Solution Temperature Stimuli-responsive Polymer Photoresponsive Stimuli-sensitive Ph-responsive Polymers Thermoresponsive Water-soluble Polymers |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.24034 |
| 英文摘要 | Novel water-soluble triply-responsive homopolymers of N,N-dimethylaminoethyl methacrylate (DMAEMA) containing an azobenzene moiety as the terminal group were synthesized by atom transfer radical polymerization (ATRP) technique The ATRP process of DMAEMA was initiated by an azobenzene derivative substituted with a 2-bromoisobutyryl group (Azo-Br) in the presence of CuCl/Me(6)TREN in 1,4-dioxane as a catalyst system The molecular weights and their polydispersities of the resulting homopolymers (Azo-PDMAEMA) were characterized by gel permeation chromatography (GPC). The homopolymers are soluble in aqueous solution and exhibit a lower critical solution temperature (LCST) that alternated reversibly in response to Ph and photoisomerization of the terminal azobenzene moiety It was found that the LCST increased as pH decreased in the range of testing. Under UV light irradiation, the trans-to-cis photoisomenzation of the azobenzene moiety resulted in a higher LCST, whereas it recovered under visible light irradiation This kind of polymers should be particularly interesting for a variety of potential applications in some promising areas, such as drug controlled-releasing carriers and intelligent materials because of the multistimuli responsive property (C) 2010 Wiley Periodicals, Inc J Polym Sci Part A Polym Chem 48 2564-2570, 2010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000278750500006 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70101]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Xinde |
| 作者单位 | 1.Shandong Jiaotong Univ, Inst New Mat, Jinan 250023, Peoples R China 2.Peking Univ, Dept Polymer Sci & Engn, Coll Chem & Mol Engn, BNLMS,Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Xinde,Liang, Xiaochao,Gao, Longcheng,et al. Water-Soluble Triply-Responsive Homopolymers of N,N-Dimethylaminoethyl methacrylate with a Terminal Azobenzene Moiety[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2010,48(12):2564-2570. |
| APA | Tang, Xinde,Liang, Xiaochao,Gao, Longcheng,Fan, Xinghe,&Zhou, Qifeng.(2010).Water-Soluble Triply-Responsive Homopolymers of N,N-Dimethylaminoethyl methacrylate with a Terminal Azobenzene Moiety.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,48(12),2564-2570. |
| MLA | Tang, Xinde,et al."Water-Soluble Triply-Responsive Homopolymers of N,N-Dimethylaminoethyl methacrylate with a Terminal Azobenzene Moiety".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 48.12(2010):2564-2570. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。