中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A multiphasic model for the volume change of polyelectrolyte hydrogels

文献类型:期刊论文

作者Feng, Ligang1; Jia, Yuxi1,2; Chen, Xiliang1; Li, Xue3; An, Lijia2
刊名JOURNAL OF CHEMICAL PHYSICS
出版日期2010-09-21
卷号133期号:11
关键词Damping Diffusion Elasticity Finite Element Analysis Friction Hydrogels Polymer Electrolytes Swelling
ISSN号0021-9606
DOI10.1063/1.3484236
英文摘要A multiphasic model for the volume change of polyelectrolyte hydrogels that takes into account conservation of mass and momentum is derived. The gradient of chemical/electrochemical potentials of water and mobile ions is taken as the driving force for the volume change of the polyelectrolyte hydrogel, which is damped by the frictional forces between different phases and balanced by the elastic restoring force of the polymer network. Employing the model constructed here, the free swelling of a spherical polyelectrolyte hydrogel immersed in salt solution is simulated by the finite element method. The simulation shows that the polyelectrolyte hydrogel swells from the surface to the interior when the concentration of the external salt solution decreases. The swelling kinetics for ordinary hydrogels with high frictional coefficient between the polymer network and water is controlled by the collective diffusion of the polymer network, while for fast-response hydrogels it is controlled by the ionic diffusion in the hydrogel. (C) 2010 American Institute of Physics. [doi:10.1063/1.3484236]
语种英语
WOS记录号WOS:000282047500039
出版者AMER INST PHYSICS
源URL[http://ir.iccas.ac.cn/handle/121111/70145]  
专题中国科学院化学研究所
通讯作者Jia, Yuxi
作者单位1.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
3.Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China
推荐引用方式
GB/T 7714
Feng, Ligang,Jia, Yuxi,Chen, Xiliang,et al. A multiphasic model for the volume change of polyelectrolyte hydrogels[J]. JOURNAL OF CHEMICAL PHYSICS,2010,133(11).
APA Feng, Ligang,Jia, Yuxi,Chen, Xiliang,Li, Xue,&An, Lijia.(2010).A multiphasic model for the volume change of polyelectrolyte hydrogels.JOURNAL OF CHEMICAL PHYSICS,133(11).
MLA Feng, Ligang,et al."A multiphasic model for the volume change of polyelectrolyte hydrogels".JOURNAL OF CHEMICAL PHYSICS 133.11(2010).

入库方式: OAI收割

来源:化学研究所

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