A melamine-adipate-bridged binuclear copper complex with supramolecular architecture: synthesis, structures, and properties of [Cu-2(MA)(ad)(2)]center dot EH2O and (MA)E(H(2)ad)center dot EH2O
文献类型:期刊论文
作者 | Zhao, Hai-Yan1; Bai, Feng-Ying1; Xing, Yong-Heng1; Li, Zhang-Peng1; Cao, Yun-Zhu1; Zeng, Xiao-Qing2; Ge, Mao-Fa2 |
刊名 | JOURNAL OF COORDINATION CHEMISTRY
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出版日期 | 2010 |
卷号 | 63期号:3页码:435-447 |
关键词 | Melamine Synthesis Supramolecular Complexes Crystal Structure Hydrogen Bonds |
ISSN号 | 0095-8972 |
DOI | 10.1080/00958970903437024 |
英文摘要 | Complexes of melamine with adipic acid and Cu(CH3COO)2 center dot H2O, [Cu2(MA)(ad)2] center dot H2O (1), and (MA) center dot (H2ad) center dot H2O (2) (MA = melamine; H2ad = adipic acid) have been synthesized under hydrothermal conditions and characterized by elemental analysis, infrared, UV-Vis, and single crystal X-ray diffraction. Both crystallized in the triclinic space group P-1. In 1, MA and adipate bond to copper to construct a 3-D supramolecular framework in an unusual noninterpenetrated pseudo-primitive cubic topology constructed from a four-connected binuclear Cu(II) secondary building unit. A variety of intra- or inter-molecular hydrogen bonds exist. In 2, the 3-D supramolecular structure is formed through strong interactions among MA, adipic acid, and lattice water. Thermal analysis, photoluminescence, and calculations were also performed. |
语种 | 英语 |
WOS记录号 | WOS:000275029100006 |
出版者 | TAYLOR & FRANCIS LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/70231] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xing, Yong-Heng |
作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalia 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Hai-Yan,Bai, Feng-Ying,Xing, Yong-Heng,et al. A melamine-adipate-bridged binuclear copper complex with supramolecular architecture: synthesis, structures, and properties of [Cu-2(MA)(ad)(2)]center dot EH2O and (MA)E(H(2)ad)center dot EH2O[J]. JOURNAL OF COORDINATION CHEMISTRY,2010,63(3):435-447. |
APA | Zhao, Hai-Yan.,Bai, Feng-Ying.,Xing, Yong-Heng.,Li, Zhang-Peng.,Cao, Yun-Zhu.,...&Ge, Mao-Fa.(2010).A melamine-adipate-bridged binuclear copper complex with supramolecular architecture: synthesis, structures, and properties of [Cu-2(MA)(ad)(2)]center dot EH2O and (MA)E(H(2)ad)center dot EH2O.JOURNAL OF COORDINATION CHEMISTRY,63(3),435-447. |
MLA | Zhao, Hai-Yan,et al."A melamine-adipate-bridged binuclear copper complex with supramolecular architecture: synthesis, structures, and properties of [Cu-2(MA)(ad)(2)]center dot EH2O and (MA)E(H(2)ad)center dot EH2O".JOURNAL OF COORDINATION CHEMISTRY 63.3(2010):435-447. |
入库方式: OAI收割
来源:化学研究所
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