Cholesterol-substituted Tetrathiafulvalene (TTF) Compound: Formation of Organogel and Supramolecular Chirality
文献类型：期刊论文
| 作者 | Wang Cheng; Sun Fei; Zhang Deqing; Zhang Guanxin; Zhu Daoben |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2010-04-01 |
| 卷号 | 28期号:4页码:622-626 |
| 关键词 | Tetrathiafulvalene Gel Self-assembly |
| ISSN号 | 1001-604X |
| 英文摘要 | A new tetrathiafulvalene (TTF) derivative with two cholesterol units (compound 1) was synthesized and characterized. Gelation of n-hexane occurred after the hot solution of 1 was subjected to ultrasonic treatment for a few minutes. The resulting organogel was characterized with SEM, XRD and AFM. Besides heating the gel-sal transition also occurred upon addition of 12 which can oxidize the TTF unit in 1. This result provides a new example of organogels responding to redox reactions. Interestingly, gelation-induced CD signals were observed and the CD signals can be tuned with the gel-sal transition which can be effected by heating and chemical reaction with I(2). |
| 语种 | 英语 |
| WOS记录号 | WOS:000277483800022 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70401]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang Deqing |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Organ Solids Lab, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Cheng,Sun Fei,Zhang Deqing,et al. Cholesterol-substituted Tetrathiafulvalene (TTF) Compound: Formation of Organogel and Supramolecular Chirality[J]. CHINESE JOURNAL OF CHEMISTRY,2010,28(4):622-626. |
| APA | Wang Cheng,Sun Fei,Zhang Deqing,Zhang Guanxin,&Zhu Daoben.(2010).Cholesterol-substituted Tetrathiafulvalene (TTF) Compound: Formation of Organogel and Supramolecular Chirality.CHINESE JOURNAL OF CHEMISTRY,28(4),622-626. |
| MLA | Wang Cheng,et al."Cholesterol-substituted Tetrathiafulvalene (TTF) Compound: Formation of Organogel and Supramolecular Chirality".CHINESE JOURNAL OF CHEMISTRY 28.4(2010):622-626. |
入库方式： OAI收割
来源：化学研究所
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