Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes
文献类型：期刊论文
| 作者 | Ban, Shurong1,2; Du, Da-Ming1; Liu, Han3; Yang, Wen1 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2010-09-01 |
| 期号 | 27页码:5160-5164 |
| 关键词 | Sulfonamides Organocatalysis Enantioselectivity Michael Addition Alkenes |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201000818 |
| 英文摘要 | Novel types of L-proline-based binaphthyl sulfonimides and sulfonamides were found to be efficient organocatalysts for the asymmetric Michael addition of ketones to nitroalkenes to provide optically active gamma-nitroketone derivatives of synthetic and biological importance. After the fine optimization of solvents, temperature, and additive, good to excellent enantioselectivities and diastereoselectivities (71-96 % ee, up to >99:1 dr) can be achieved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000283102700003 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70407]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, Da-Ming |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China 2.Shanxi Med Univ, Sch Pharmaceut Sci, Taiyuan 030001, Peoples R China 3.Peking Univ, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ban, Shurong,Du, Da-Ming,Liu, Han,et al. Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2010(27):5160-5164. |
| APA | Ban, Shurong,Du, Da-Ming,Liu, Han,&Yang, Wen.(2010).Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(27),5160-5164. |
| MLA | Ban, Shurong,et al."Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .27(2010):5160-5164. |
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来源：化学研究所
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