中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sensitized luminescence from lanthanides in d-f bimetallic complexes

文献类型:期刊论文

作者Chen, Fang-Fang; Chen, Zhu-Qi; Bian, Zu-Qiang; Huang, Chun-Hui
刊名COORDINATION CHEMISTRY REVIEWS
出版日期2010-05-01
卷号254期号:9-10页码:991-1010
关键词Bimetallic Complexes Transition Metals Lanthanides Red Emission Nir Emission
ISSN号0010-8545
DOI10.1016/j.ccr.2009.12.028
英文摘要This article reviews progress in the research of transition metal-lanthanide (d-f) bimetallic complexes Through efficient energy transfer, sensitized luminescence of lanthanide ions from the visible range (Eu(III)) to the near-infrared region (Nd(III), Yb(III), Er(III) and Pr(III)) is obtained in these bimetallic assembles The d-block in d-f bimetallic complexes mainly contributes to the improvement of lanthanide emission efficiency and the extension of the excitation window for the lanthanide complexes. Examples are catalogued by various transition metals, such as Ru(II), Os(II) (Fe(II)), Pt(II) (Au(I)), Pd(II), Cr(III), Co(III), Zn(II) and Ir(III). The relevant synthetic procedures, crystal structures and photophysical properties of these d-f complexes are briefly described Additionally, the molecular properties responsible for the performance of certain d-f systems, such as energy levels, nuclear distances and coordination environments, will be discussed (C) 2009 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000276380800005
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/70455]  
专题中国科学院化学研究所
通讯作者Huang, Chun-Hui
作者单位Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,et al. Sensitized luminescence from lanthanides in d-f bimetallic complexes[J]. COORDINATION CHEMISTRY REVIEWS,2010,254(9-10):991-1010.
APA Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,&Huang, Chun-Hui.(2010).Sensitized luminescence from lanthanides in d-f bimetallic complexes.COORDINATION CHEMISTRY REVIEWS,254(9-10),991-1010.
MLA Chen, Fang-Fang,et al."Sensitized luminescence from lanthanides in d-f bimetallic complexes".COORDINATION CHEMISTRY REVIEWS 254.9-10(2010):991-1010.

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来源:化学研究所

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