A fluorescent conjugated polymer for trace detection of diamines and biogenic polyamines
文献类型：期刊论文
| 作者 | Bao, Biqing2,3; Yuwen, Lihui2,3; Zheng, Xiannuo1; Weng, Lixing1; Zhu, Xingrong2,3; Zhan, Xiaowei4,5; Wang, Lianhui2,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 20期号:43页码:9628-9634 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/c0jm01467b |
| 英文摘要 | The aggregation-based trace detection of diamines and biogenic polyamines has been developed utilizing a carboxylic acid-functionalized polyfluorene (PFCOOH-BT(5)) containing benzo[2,1,3] thiadiazole (BT). Upon addition of diamines or biogenic polyamines, the PFCOOH-BT(5) can be cross-linked via electrostatic interactions between the polymer carboxylic acid binding sites and the amino groups of the multiamines to form interpolymer aggregation, which leads to more efficient FRET from fluorene segments to BT units and thus a noticeable fluorescence color change from blue to orange. In contrast, addition of 1,3-propanediol does not lead to significant variations in the photoluminescence spectra of PFCOOH-BT(5). This unique fluorescence response from PFCOOH-BT(5) to diamines and biogenic polyamines can achieve a detection concentration as low as 2 mu M, indicating that PFCOOH-BT(5) can serve as a general and effective chemosensor to detect trace diamines and biogenic polyamines. |
| 语种 | 英语 |
| WOS记录号 | WOS:000283603000009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70553]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Weng, Lixing |
| 作者单位 | 1.Fudan Univ, Sch Life Sci, Shanghai 200433, Peoples R China 2.Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China 3.Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China 4.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bao, Biqing,Yuwen, Lihui,Zheng, Xiannuo,et al. A fluorescent conjugated polymer for trace detection of diamines and biogenic polyamines[J]. JOURNAL OF MATERIALS CHEMISTRY,2010,20(43):9628-9634. |
| APA | Bao, Biqing.,Yuwen, Lihui.,Zheng, Xiannuo.,Weng, Lixing.,Zhu, Xingrong.,...&Wang, Lianhui.(2010).A fluorescent conjugated polymer for trace detection of diamines and biogenic polyamines.JOURNAL OF MATERIALS CHEMISTRY,20(43),9628-9634. |
| MLA | Bao, Biqing,et al."A fluorescent conjugated polymer for trace detection of diamines and biogenic polyamines".JOURNAL OF MATERIALS CHEMISTRY 20.43(2010):9628-9634. |
入库方式： OAI收割
来源：化学研究所
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